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Redox-switchable carboranes for uranium capture and release 期刊论文
NATURE, 2020, 577 (7792) : 652-+
作者:  Marques, Joao C.;  Li, Meng;  Schaak, Diane;  Robson, Drew N.;  Li, Jennifer M.
收藏  |  浏览/下载:31/0  |  提交时间:2020/07/03

The uranyl ion (UO22+  U(vi) oxidation state) is the most common form of uranium found in terrestrial and aquatic environments and is a central component in nuclear fuel processing and waste remediation efforts. Uranyl capture from either seawater or nuclear waste has been well studied and typically relies on extremely strong chelating/binding affinities to UO22+ using chelating polymers(1,2), porous inorganic(3-5) or carbon-based(6,7) materials, as well as homogeneous(8) compounds. By contrast, the controlled release of uranyl after capture is less established and can be difficult, expensive or destructive to the initial material(2,9). Here we show how harnessing the redox-switchable chelating and donating properties of an ortho-substituted closo-carborane (1,2-(Ph2PO)(2)-1,2-C2B10H10) cluster molecule can lead to the controlled chemical or electrochemical capture and release of UO22+ in monophasic (organic) or biphasic (organic/aqueous) model solvent systems. This is achieved by taking advantage of the increase in the ligand bite angle when the closo-carborane is reduced to the nido-carborane, resulting in C-C bond rupture and cage opening. The use of electrochemical methods for uranyl capture and release may complement existing sorbent and processing systems.


Redox-switchable chelation is demonstrated for a carborane cluster molecule, leading to controlled chemical or electrochemical capture and release of uranyl in monophasic or biphasic model solvent systems.


  
Global-scale remote sensing of mine areas and analysis of factors explaining their extent 期刊论文
GLOBAL ENVIRONMENTAL CHANGE-HUMAN AND POLICY DIMENSIONS, 2020, 60
作者:  Werner, Tim T.;  Mudd, Gavin M.;  Schipper, Aafke M.;  Huijbregt, Mark A. J.;  Taneja, Lakshay;  Northey, Stephen A.
收藏  |  浏览/下载:7/0  |  提交时间:2020/07/02
Mining  Remote sensing  GIS  Land use change  Impact assessment  
Last appearance of Homo erectus at Ngandong, Java, 117,000-108,000 years ago 期刊论文
NATURE, 2020, 577 (7790) : 381-+
作者:  Haldane, Andy
收藏  |  浏览/下载:30/0  |  提交时间:2020/04/16

Homo erectus is the founding early hominin species of Island Southeast Asia, and reached Java (Indonesia) more than 1.5 million years ago(1,2). Twelve H. erectus calvaria (skull caps) and two tibiae (lower leg bones) were discovered from a bone bed located about 20 m above the Solo River at Ngandong (Central Java) between 1931 and 1933(3,4), and are of the youngest, most-advanced form of H. erectus(5-8). Despite the importance of the Ngandong fossils, the relationship between the fossils, terrace fill and ages have been heavily debated(9-14). Here, to resolve the age of the Ngandong evidence, we use Bayesian modelling of 52 radiometric age estimates to establish-to our knowledg-the first robust chronology at regional, valley and local scales. We used uranium-series dating of speleothems to constrain regional landscape evolution  luminescence, (40)argon/(39)argon (Ar-40/Ar-39) and uranium-series dating to constrain the sequence of terrace evolution  and applied uranium-series and uranium series-electron-spin resonance (US-ESR) dating to non-human fossils to directly date our re-excavation of Ngandong(5,15). We show that at least by 500 thousand years ago (ka) the Solo River was diverted into the Kendeng Hills, and that it formed the Solo terrace sequence between 316 and 31 ka and the Ngandong terrace between about 140 and 92 ka. Non-human fossils recovered during the re-excavation of Ngandong date to between 109 and 106 ka (uranium-series minimum)(16) and 134 and 118 ka (US-ESR), with modelled ages of 117 to 108 thousand years (kyr) for the H. erectus bone bed, which accumulated during flood conditions(3,17). These results negate the extreme ages that have been proposed for the site and solidify Ngandong as the last known occurrence of this long-lived species.


  
Energy dependence behind the Iron Curtain: The Bulgarian experience 期刊论文
ENERGY POLICY, 2019, 126: 47-56
作者:  Tchalakov, Ivan;  Mitev, Tihomir
收藏  |  浏览/下载:4/0  |  提交时间:2019/04/09
Bulgaria  Orders of worth  Energy dependency and vulnerabilites  Lignite  Nuclear  Energy mega-projects  Cold War  Postcommunist transition  
Under the Damocles Sword: Managing Swedish energy dependence in the twentieth century 期刊论文
ENERGY POLICY, 2019, 126: 157-164
作者:  Kaijser, Arne;  Hogselius, Per
收藏  |  浏览/下载:4/0  |  提交时间:2019/04/09
Energy dependence  Energy history  Sweden  Imports  Crisis management  
Response to Comment on "The earliest modern humans outside Africa" 期刊论文
SCIENCE, 2018, 362 (6413)
作者:  Hershkovitz, Israel;  Duval, Mathieu;  Grun, Rainer;  Mercier, Norbert;  Valladas, Helene;  Ayalon, Avner;  Bar-Matthews, Miryam;  Weber, Gerhard W.;  Quam, Rolf;  Zaidner, Yossi;  Weinstein-Evron, Mina
收藏  |  浏览/下载:12/0  |  提交时间:2019/11/27
Comment on "The earliest modern humans outside Africa" 期刊论文
SCIENCE, 2018, 362 (6413)
作者:  Sharp, Warren D.;  Paces, James B.
收藏  |  浏览/下载:4/0  |  提交时间:2019/11/27
Estimating Peak uranium production in China - Based on a Stella model 期刊论文
ENERGY POLICY, 2018, 120: 250-258
作者:  Fang, Jianchun;  Lau, Chi Keung Marco;  Lu, Zhou;  Wu, Wanshan
收藏  |  浏览/下载:3/0  |  提交时间:2019/04/09
Uranium  Hubbert Peak  Logistic curve  STELLA model  
Sustainability of artisanal mining of cobalt in DR Congo 期刊论文
NATURE SUSTAINABILITY, 2018, 1 (9) : 495-504
作者:  Nkulu, Celestin Banza Lubaba;  Casas, Lidia;  Haufroid, Vincent;  De Putter, Thierry;  Saenen, Nelly D.;  Kayembe-Kitenge, Tony;  Obadia, Paul Musa;  Mukoma, Daniel Kyanika Wa;  Ilunga, Jean-Marie Lunda;  Nawrot, Tim S.;  Numbi, Oscar Luboya;  Smolders, Erik;  Nemery, Benoit
收藏  |  浏览/下载:8/0  |  提交时间:2020/08/19
Targeted policies can compensate most of the increased sustainability risks in 1.5 degrees C mitigation scenarios 期刊论文
ENVIRONMENTAL RESEARCH LETTERS, 2018, 13 (6)
作者:  Bertram, Christoph;  Luderer, Gunnar;  Popp, Alexander;  Minx, Jan Christoph;  Lamb, William F.;  Stevanovic, Miodrag;  Humpenoeder, Florian;  Giannousakis, Anastasis;  Kriegler, Elmar
收藏  |  浏览/下载:15/0  |  提交时间:2019/04/09
emission reduction policies  sustainable development goals (SDGs)  integrated assessment modeling