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Metallic glasses that harden under strain 期刊论文
NATURE, 2020, 578 (7796) : 521-522
作者:  Keller, Andreas J.;  Roth, Morgane M.;  Scanziani, Massimo
收藏  |  浏览/下载:10/0  |  提交时间:2020/07/03

A process that reduces the risk of metallic glasses failing under stress.


Metallic glasses are much stronger than conventional metals, but form certain instabilities under stress that lead to fracture. A process known as rejuvenation has been shown to solve this problem.


  
Boundaries transformed in pure metals 期刊论文
NATURE, 2020, 579 (7799) : 350-351
作者:  Ledford, Heidi
收藏  |  浏览/下载:3/0  |  提交时间:2020/07/03

Interfaces between the tiny crystal grains that make up solid copper have been shown to change from one ordered phase to another, independently of the phase adopted by the crystals, opening up prospects for materials development.


Polymorphs of grain boundaries in copper visualized and modelled.


  
Early atmospheric contamination on the top of the Himalayas since the onset of the European Industrial Revolution 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2020, 117 (8) : 3967-3973
作者:  Gabrielli, Paolo;  Wegner, Anna;  Sierra-Hernandez, M. Roxana;  Beaudon, Emilie;  Davis, Mary;  Barker, Joel D.;  Thompson, Lonnie G.
收藏  |  浏览/下载:8/0  |  提交时间:2020/05/13
ice cores  trace metals  paleoenvironment  monsoon  North Atlantic Oscillation  
Redox-switchable carboranes for uranium capture and release 期刊论文
NATURE, 2020, 577 (7792) : 652-+
作者:  Marques, Joao C.;  Li, Meng;  Schaak, Diane;  Robson, Drew N.;  Li, Jennifer M.
收藏  |  浏览/下载:31/0  |  提交时间:2020/07/03

The uranyl ion (UO22+  U(vi) oxidation state) is the most common form of uranium found in terrestrial and aquatic environments and is a central component in nuclear fuel processing and waste remediation efforts. Uranyl capture from either seawater or nuclear waste has been well studied and typically relies on extremely strong chelating/binding affinities to UO22+ using chelating polymers(1,2), porous inorganic(3-5) or carbon-based(6,7) materials, as well as homogeneous(8) compounds. By contrast, the controlled release of uranyl after capture is less established and can be difficult, expensive or destructive to the initial material(2,9). Here we show how harnessing the redox-switchable chelating and donating properties of an ortho-substituted closo-carborane (1,2-(Ph2PO)(2)-1,2-C2B10H10) cluster molecule can lead to the controlled chemical or electrochemical capture and release of UO22+ in monophasic (organic) or biphasic (organic/aqueous) model solvent systems. This is achieved by taking advantage of the increase in the ligand bite angle when the closo-carborane is reduced to the nido-carborane, resulting in C-C bond rupture and cage opening. The use of electrochemical methods for uranyl capture and release may complement existing sorbent and processing systems.


Redox-switchable chelation is demonstrated for a carborane cluster molecule, leading to controlled chemical or electrochemical capture and release of uranyl in monophasic or biphasic model solvent systems.


  
Comment on "Observation of alkaline earth complexes M(CO)(8)(M = Ca, Sr, or Ba) that mimic transition metals" 期刊论文
SCIENCE, 2019, 365 (6453)
作者:  Landis, Clark R.;  Hughes, Russell P.;  Weinhold, Frank
收藏  |  浏览/下载:6/0  |  提交时间:2019/11/27
Response to Comment on "Observation of alkaline earth complexes M(CO)(8)(M = Ca, Sr, or Ba) that mimic transition metals" 期刊论文
SCIENCE, 2019, 365 (6453)
作者:  Zhao, Lili;  Pan, Sudip;  Zhou, Mingfei;  Frenking, Gernot
收藏  |  浏览/下载:4/0  |  提交时间:2019/11/27
Pervasive Arctic lead pollution suggests substantial growth in medieval silver production modulated by plague, climate, and conflict 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (30) : 14910-14915
作者:  McConnell, Joseph R.;  Chellman, Nathan J.;  Wilson, Andrew I.;  Stohl, Andreas;  Arienzo, Monica M.;  Eckhardt, Sabine;  Fritzsche, Diedrich;  Kipfstuhl, Sepp;  Opel, Thomas;  Place, Philip F.;  Steffensen, Jorgen Peder
收藏  |  浏览/下载:8/0  |  提交时间:2019/11/27
ice core  lead pollution  Arctic  plague  Middle Ages  
Improving sustainability with simpler alloys 期刊论文
SCIENCE, 2019, 364 (6442) : 733-734
作者:  Li, Xiuyan;  Lu, K.
收藏  |  浏览/下载:1/0  |  提交时间:2019/11/27
Material efficiency strategies to reducing greenhouse gas emissions associated with buildings, vehicles, and electronics-a review 期刊论文
ENVIRONMENTAL RESEARCH LETTERS, 2019, 14 (4)
作者:  Hertwich, Edgar G.;  Ali, Saleem;  Ciacci, Luca;  Fishman, Tomer;  Heeren, Niko;  Masanet, Eric;  Asghari, Farnaz Nojavan;  Olivetti, Elsa;  Pauliuk, Stefan;  Tu, Qingshi;  Wolfram, Paul
收藏  |  浏览/下载:12/0  |  提交时间:2019/11/26
circular economy  climate change mitigation  life cycle assessment  industrial policy  resource efficiency  cement  iron and steel  
Lead isotopes in silver reveal earliest Phoenician quest for metals in the west Mediterranean 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (13) : 6007-6012
作者:  Eshel, Tzilla;  Erel, Yigal;  Yahalom-Mack, Naama;  Tirosh, Ofir;  Gilboa, Ayelet
收藏  |  浏览/下载:8/0  |  提交时间:2019/11/27
silver  lead isotope analysis  Phoenicians  Sardinia  Iberia