GSTDTAP

浏览/检索结果: 共154条,第1-10条 帮助

限定条件                
已选(0)清除 条数/页:   排序方式:
Potential for large-scale CO2 removal via enhanced rock weathering with croplands 期刊论文
NATURE, 2020, 583 (7815) : 242-+
作者:  David J. Beerling;  Euripides P. Kantzas;  Mark R. Lomas;  Peter Wade;  Rafael M. Eufrasio;  Phil Renforth;  Binoy Sarkar;  M. Grace Andrews;  Rachael H. James;  Christopher R. Pearce;  Jean-Francois Mercure;  Hector Pollitt;  Philip B. Holden;  Neil R. Edwards;  Madhu Khanna;  Lenny Koh;  Shaun Quegan;  Nick F. Pidgeon;  Ivan A. Janssens;  James Hansen;  Steven A. Banwart
收藏  |  浏览/下载:18/0  |  提交时间:2020/07/14

Enhanced silicate rock weathering (ERW), deployable with croplands, has potential use for atmospheric carbon dioxide (CO2) removal (CDR), which is now necessary to mitigate anthropogenic climate change(1). ERW also has possible co-benefits for improved food and soil security, and reduced ocean acidification(2-4). Here we use an integrated performance modelling approach to make an initial techno-economic assessment for 2050, quantifying how CDR potential and costs vary among nations in relation to business-as-usual energy policies and policies consistent with limiting future warming to 2 degrees Celsius(5). China, India, the USA and Brazil have great potential to help achieve average global CDR goals of 0.5 to 2gigatonnes of carbon dioxide (CO2) per year with extraction costs of approximately US$80-180 per tonne of CO2. These goals and costs are robust, regardless of future energy policies. Deployment within existing croplands offers opportunities to align agriculture and climate policy. However, success will depend upon overcoming political and social inertia to develop regulatory and incentive frameworks. We discuss the challenges and opportunities of ERW deployment, including the potential for excess industrial silicate materials (basalt mine overburden, concrete, and iron and steel slag) to obviate the need for new mining, as well as uncertainties in soil weathering rates and land-ocean transfer of weathered products.


  
Progressive nitrogen limitation across the Tibetan alpine permafrost region 期刊论文
NATURE COMMUNICATIONS, 2020, 11 (1)
作者:  Kou, Dan;  Yang, Guibiao;  Li, Fei;  Feng, Xuehui;  Zhang, Dianye;  Mao, Chao;  Zhang, Qiwen;  Peng, Yunfeng;  Ji, Chengjun;  Zhu, Qiuan;  Fang, Yunting;  Liu, Xueyan;  Xu-Ri;  Li, Siqi;  Deng, Jia;  Zheng, Xunhua;  Fang, Jingyun;  Yang, Yuanhe
收藏  |  浏览/下载:18/0  |  提交时间:2020/07/06
International evaluation of an AI system for breast cancer screening 期刊论文
NATURE, 2020, 577 (7788) : 89-+
作者:  McKinney, Scott Mayer;  Sieniek, Marcin;  Godbole, Varun;  Godwin, Jonathan;  Antropova, Natasha;  Ashrafian, Hutan;  Back, Trevor;  Chesus, Mary;  Corrado, Greg C.;  Darzi, Ara;  Etemadi, Mozziyar;  Garcia-Vicente, Florencia;  Gilbert, Fiona J.;  Halling-Brown, Mark;  Hassabis, Demis;  Jansen, Sunny;  Karthikesalingam, Alan;  Kelly, Christopher J.;  King, Dominic;  Ledsam, Joseph R.;  Melnick, David;  Mostofi, Hormuz;  Peng, Lily;  Reicher, Joshua Jay;  Romera-Paredes, Bernardino;  Sidebottom, Richard;  Suleyman, Mustafa;  Tse, Daniel;  Young, Kenneth C.;  De Fauw, Jeffrey;  Shetty, Shravya
收藏  |  浏览/下载:15/0  |  提交时间:2020/07/03

Screening mammography aims to identify breast cancer at earlier stages of the disease, when treatment can be more successful(1). Despite the existence of screening programmes worldwide, the interpretation of mammograms is affected by high rates of false positives and false negatives(2). Here we present an artificial intelligence (AI) system that is capable of surpassing human experts in breast cancer prediction. To assess its performance in the clinical setting, we curated a large representative dataset from the UK and a large enriched dataset from the USA. We show an absolute reduction of 5.7% and 1.2% (USA and UK) in false positives and 9.4% and 2.7% in false negatives. We provide evidence of the ability of the system to generalize from the UK to the USA. In an independent study of six radiologists, the AI system outperformed all of the human readers: the area under the receiver operating characteristic curve (AUC-ROC) for the AI system was greater than the AUC-ROC for the average radiologist by an absolute margin of 11.5%. We ran a simulation in which the AI system participated in the double-reading process that is used in the UK, and found that the AI system maintained non-inferior performance and reduced the workload of the second reader by 88%. This robust assessment of the AI system paves the way for clinical trials to improve the accuracy and efficiency of breast cancer screening.


  
Ecological drivers of global gradients in avian dispersal inferred from wing morphology 期刊论文
NATURE COMMUNICATIONS, 2020, 11 (1)
作者:  Sheard, Catherine;  Neate-Clegg, Montague H. C.;  Alioravainen, Nico;  Jones, Samuel E., I;  Vincent, Claire;  MacGregor, Hannah E. A.;  Bregman, Tom P.;  Claramunt, Santiago;  Tobias, Joseph A.
收藏  |  浏览/下载:13/0  |  提交时间:2020/05/20
Increased drought severity tracks warming in the United States' largest river basin 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2020, 117 (21) : 11328-11336
作者:  Martin, Justin T.;  Pederson, Gregory T.;  Woodhouse, Connie A.;  Cook, Edward R.;  McCabe, Gregory J.;  Anchukaitis, Kevin J.;  Wise, Erika K.;  Erger, Patrick J.;  Dolan, Larry;  McGuire, Marketa;  Gangopadhyay, Subhrendu;  Chase, Katherine J.;  Littell, Jeremy S.;  Gray, Stephen T.;  George, Scott St.;  Friedman, Jonathan M.;  Sauchyn, David J.;  St-Jacques, Jeannine-Marie;  King, John
收藏  |  浏览/下载:14/0  |  提交时间:2020/05/13
drought severity  streamflow  temperature  precipitation  water resources  
Improvement in municipal wastewater treatment alters lake nitrogen to phosphorus ratios in populated regions 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2020, 117 (21) : 11566-11572
作者:  Tong, Yindong;  Wang, Mengzhu;  Penuelas, Josep;  Liu, Xueyan;  Paerl, Hans W.;  Elser, James J.;  Sardans, Jordi;  Couture, Raoul-Marie;  Larssen, Thorjorn;  Hu, Hongying;  Dong, Xin;  He, Wei;  Zhang, Wei;  Wang, Xuejun;  Zhang, Yang;  Liu, Yi;  Zeng, Siyu;  Kong, Xiangzhen;  Janssen, Annette B. G.;  Lin, Yan
收藏  |  浏览/下载:12/0  |  提交时间:2020/05/13
nutrient balance  water quality change  anthropogenic source  wastewater treatment  aquatic ecosystem  
Molecular tuning of CO2-to-ethylene conversion 期刊论文
NATURE, 2020, 577 (7791) : 509-+
作者:  Li, Fengwang;  39;Brien, Colin P.
收藏  |  浏览/下载:11/0  |  提交时间:2020/07/03

The electrocatalytic reduction of carbon dioxide, powered by renewable electricity, to produce valuable fuels and feedstocks provides a sustainable and carbon-neutral approach to the storage of energy produced by intermittent renewable sources(1). However, the highly selective generation of economically desirable products such as ethylene from the carbon dioxide reduction reaction (CO2RR) remains a challenge(2). Tuning the stabilities of intermediates to favour a desired reaction pathway can improve selectivity(3-5), and this has recently been explored for the reaction on copper by controlling morphology(6), grain boundaries(7), facets(8), oxidation state(9) and dopants(10). Unfortunately, the Faradaic efficiency for ethylene is still low in neutral media (60 per cent at a partial current density of 7 milliamperes per square centimetre in the best catalyst reported so far(9)), resulting in a low energy efficiency. Here we present a molecular tuning strategy-the functionalization of the surface of electrocatalysts with organic molecules-that stabilizes intermediates for more selective CO2RR to ethylene. Using electrochemical, operando/in situ spectroscopic and computational studies, we investigate the influence of a library of molecules, derived by electro-dimerization of arylpyridiniums(11), adsorbed on copper. We find that the adhered molecules improve the stabilization of an '  atop-bound'  CO intermediate (that is, an intermediate bound to a single copper atom), thereby favouring further reduction to ethylene. As a result of this strategy, we report the CO2RR to ethylene with a Faradaic efficiency of 72 per cent at a partial current density of 230 milliamperes per square centimetre in a liquid-electrolyte flow cell in a neutral medium. We report stable ethylene electrosynthesis for 190 hours in a system based on a membrane-electrode assembly that provides a full-cell energy efficiency of 20 per cent. We anticipate that this may be generalized to enable molecular strategies to complement heterogeneous catalysts by stabilizing intermediates through local molecular tuning.


Electrocatalytic reduction of CO2 over copper can be made highly selective by '  tuning'  the copper surface with adsorbed organic molecules to stabilize intermediates for carbon-based fuels such as ethylene


  
Accelerated discovery of CO2 electrocatalysts using active machine learning 期刊论文
NATURE, 2020, 581 (7807) : 178-+
作者:  Lan, Jun;  Ge, Jiwan;  Yu, Jinfang;  Shan, Sisi;  Zhou, Huan;  Fan, Shilong;  Zhang, Qi;  Shi, Xuanling;  Wang, Qisheng;  Zhang, Linqi;  Wang, Xinquan
收藏  |  浏览/下载:89/0  |  提交时间:2020/07/03

The rapid increase in global energy demand and the need to replace carbon dioxide (CO2)-emitting fossil fuels with renewable sources have driven interest in chemical storage of intermittent solar and wind energy(1,2). Particularly attractive is the electrochemical reduction of CO2 to chemical feedstocks, which uses both CO2 and renewable energy(3-8). Copper has been the predominant electrocatalyst for this reaction when aiming for more valuable multi-carbon products(9-16), and process improvements have been particularly notable when targeting ethylene. However, the energy efficiency and productivity (current density) achieved so far still fall below the values required to produce ethylene at cost-competitive prices. Here we describe Cu-Al electrocatalysts, identified using density functional theory calculations in combination with active machine learning, that efficiently reduce CO2 to ethylene with the highest Faradaic efficiency reported so far. This Faradaic efficiency of over 80 per cent (compared to about 66 per cent for pure Cu) is achieved at a current density of 400 milliamperes per square centimetre (at 1.5 volts versus a reversible hydrogen electrode) and a cathodic-side (half-cell) ethylene power conversion efficiency of 55 +/- 2 per cent at 150 milliamperes per square centimetre. We perform computational studies that suggest that the Cu-Al alloys provide multiple sites and surface orientations with near-optimal CO binding for both efficient and selective CO2 reduction(17). Furthermore, in situ X-ray absorption measurements reveal that Cu and Al enable a favourable Cu coordination environment that enhances C-C dimerization. These findings illustrate the value of computation and machine learning in guiding the experimental exploration of multi-metallic systems that go beyond the limitations of conventional single-metal electrocatalysts.


  
Taking stock of national climate policies to evaluate implementation of the Paris Agreement 期刊论文
NATURE COMMUNICATIONS, 2020, 11 (1)
作者:  Roelfsema, Mark;  van Soest, Heleen L.;  Harmsen, Mathijs;  van Vuuren, Detlef P.;  Bertram, Christoph;  den Elzen, Michel;  Hoehne, Niklas;  Iacobuta, Gabriela;  Krey, Volker;  Kriegler, Elmar;  Luderer, Gunnar;  Riahi, Keywan;  Ueckerdt, Falko;  Despres, Jacques;  Drouet, Laurent;  Emmerling, Johannes;  Frank, Stefan;  Fricko, Oliver;  Gidden, Matthew;  Humpenoeder, Florian;  Huppmann, Daniel;  Fujimori, Shinichiro;  Fragkiadakis, Kostas;  Gi, Keii;  Keramidas, Kimon;  Koberle, Alexandre C.;  Reis, Lara Aleluia;  Rochedo, Pedro;  Schaeffer, Roberto;  Oshiro, Ken;  Vrontisi, Zoi;  Chen, Wenying;  Iyer, Gokul C.;  Edmonds, Jae;  Kannavou, Maria;  Jiang, Kejun;  Mathur, Ritu;  Safonoy, George;  Vishwanathan, Saritha Sudharmma
收藏  |  浏览/下载:20/0  |  提交时间:2020/05/13
Assessing the impact of ETS trading profit on emission abatements based on firm-level transactions 期刊论文
NATURE COMMUNICATIONS, 2020, 11 (1)
作者:  Guo, Jianfeng;  Gu, Fu;  Liu, Yinpeng;  Liang, Xi;  Mo, Jianlei;  Fan, Ying
收藏  |  浏览/下载:8/0  |  提交时间:2020/05/13