Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1029/2019WR027037 |
Anion diffusion in compacted clays by pore‐scale simulation and experiments | |
Tao Wu; Yuankai Yang; Zhifen Wang; Qiang Shen; Yanhua Tong; Moran Wang | |
2020-10-18 | |
发表期刊 | Water Resources Research |
出版年 | 2020 |
英文摘要 | Accurate understanding of diffusion of anionic radionuclides in different clays is significant to predict long‐term performance of high‐level radioactive waste (HLW) repositories. The importance of electrical double layer (EDL) on anionic tracer diffusion in different clays has been studied by both through‐diffusion experiments and pore‐scale simulations in this work. The through‐diffusion experiments measured the effective diffusion coefficient and the accessible porosity of Re (VII) in compacted montmorillonite, Na‐bentonite and illite/smectite mixed layer (I/S) at different salinities. The results showed that the accessible porosity and the effective diffusion coefficient of Re (VII) in montmorillonite and Na‐bentonite were similar, but lower than those in I/S under the same conditions. For mechanism analysis and predictions, a pore‐scale modeling was implemented to simulate the diffusion of anions in compacted clays. In the simulations, the characteristics (porosity, density and total surface area) of microstructures of montmorillonite and I/S were used to regenerate three‐dimensional pore structures numerically by a Quartet Structure Generation Set method. The Re (VII) diffusion was then simulated by directly solving coupled Poisson‐Nernst‐Planck equations via the lattice Boltzmann method. The diminished effect of EDL was therefore calculated and compared with Donnan and multi‐porosity models. As EDLs overlap in compacted clays, the Donnan model overestimates the influence of EDL on Re (VII) diffusion, while the multi‐porosity model underestimates it. The pore‐scale modeling, which captures the structure of overlapping EDLs automatically, can simulate the diffusion of anionic radionuclides in compacted clays without any fitting parameters. |
领域 | 资源环境 |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/300243 |
专题 | 资源环境科学 |
推荐引用方式 GB/T 7714 | Tao Wu,Yuankai Yang,Zhifen Wang,等. Anion diffusion in compacted clays by pore‐scale simulation and experiments[J]. Water Resources Research,2020. |
APA | Tao Wu,Yuankai Yang,Zhifen Wang,Qiang Shen,Yanhua Tong,&Moran Wang.(2020).Anion diffusion in compacted clays by pore‐scale simulation and experiments.Water Resources Research. |
MLA | Tao Wu,et al."Anion diffusion in compacted clays by pore‐scale simulation and experiments".Water Resources Research (2020). |
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