Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1038/s41467-018-04087-x |
Trapping an octahedral Ag-6 kernel in a seven-fold symmetric Ag-56 nanowheel | |
Wang, Zhi1,2; Su, Hai-Feng3,4; Kurmoo, Mohamedally5; Tung, Chen-Ho1,2; Sun, Di1,2; Zheng, Lan-Sun3,4 | |
2018-05-29 | |
发表期刊 | NATURE COMMUNICATIONS
![]() |
ISSN | 2041-1723 |
出版年 | 2018 |
卷号 | 9 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; France |
英文摘要 | High-nuclearity silver clusters are appealing synthetic targets for their remarkable structures, but most are isolated serendipitously. We report here six giant silver-thiolate clusters mediated by solvents, which not only dictate the formation of an octahedral Ag-6(4+) kernel, but also influence the in situ-generated Mo-based anion templates. The typical sevenfold symmetric silver nanowheels show a hierarchical cluster-in-cluster structure that comprises an outermost Ag-56 shell and an inner Ag-6(4+) kernel in the centre with seven MoO42- anion templates around it. Electrospray ionization mass spectrometry analyses reveal the underlying rule for the formation of such unique silver nanowheels. This work establishes a solvent-intervention approach to construct high-nuclearity silver clusters in which both the formation of octahedral Ag-6(4+) kernel and in situ generation of various Mo-based anion templates can be simultaneously controlled. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000433297900005 |
WOS关键词 | SILVER THIOLATE CLUSTERS ; WATER OXIDATION CATALYSTS ; CRYSTAL-STRUCTURE ; CHALCOGENIDE CLUSTERS ; NANOCLUSTER ; ANION ; SHELL ; CORE ; NANOPARTICLES ; WHEEL |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203782 |
专题 | 资源环境科学 |
作者单位 | 1.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China; 2.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China; 3.Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China; 4.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China; 5.Univ Strasbourg, CNRS, UMR 7177, Inst Chim Strasbourg, 4 Rue Blaise Pascal, F-67008 Strasbourg, France |
推荐引用方式 GB/T 7714 | Wang, Zhi,Su, Hai-Feng,Kurmoo, Mohamedally,et al. Trapping an octahedral Ag-6 kernel in a seven-fold symmetric Ag-56 nanowheel[J]. NATURE COMMUNICATIONS,2018,9. |
APA | Wang, Zhi,Su, Hai-Feng,Kurmoo, Mohamedally,Tung, Chen-Ho,Sun, Di,&Zheng, Lan-Sun.(2018).Trapping an octahedral Ag-6 kernel in a seven-fold symmetric Ag-56 nanowheel.NATURE COMMUNICATIONS,9. |
MLA | Wang, Zhi,et al."Trapping an octahedral Ag-6 kernel in a seven-fold symmetric Ag-56 nanowheel".NATURE COMMUNICATIONS 9(2018). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论