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DOI | 10.1126/science.aao0270 |
Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes | |
Wiesenfeldt, Mario P.; Nairoukh, Zackaria; Li, Wei; Glorius, Frank | |
2017-09-01 | |
发表期刊 | SCIENCE |
ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2017 |
卷号 | 357期号:6354页码:908-912 |
文章类型 | Article |
语种 | 英语 |
国家 | Germany |
英文摘要 | All-cis-multifluorinated cycloalkanes exhibit intriguing electronic properties. In particular, they display extremely high dipole moments perpendicular to the aliphatic ring, making them highly desired motifs in material science. Very few such motifs have been prepared, as their syntheses require multistep sequences from diastereoselectively prefunctionalized precursors. Herein we report a synthetic strategy to access these valuable materials via the rhodium-cyclic (alkyl)(amino)carbene (CAAC)-catalyzed hydrogenation of readily available fluorinated arenes in hexane. This route enables the scalable single-step preparation of an abundance of multisubstituted and multifluorinated cycloalkanes, including all-cis-1,2,3,4,5,6-hexafluorocyclohexane as well as cis-configured fluorinated aliphatic heterocycles. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000408734900040 |
WOS关键词 | ASYMMETRIC HYDROGENATION ; ARENE HYDROGENATION ; COMPLEXES ; FLUORINATION ; HYDRODEFLUORINATION ; CHEMISTRY ; CATALYST ; ACIDS |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/196762 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | Westfal Wilhelms Univ Munster, Organisch Chem Inst, Corrensstr 40, D-48149 Munster, Germany |
推荐引用方式 GB/T 7714 | Wiesenfeldt, Mario P.,Nairoukh, Zackaria,Li, Wei,et al. Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes[J]. SCIENCE,2017,357(6354):908-912. |
APA | Wiesenfeldt, Mario P.,Nairoukh, Zackaria,Li, Wei,&Glorius, Frank.(2017).Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes.SCIENCE,357(6354),908-912. |
MLA | Wiesenfeldt, Mario P.,et al."Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes".SCIENCE 357.6354(2017):908-912. |
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