Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.5194/acp-19-6107-2019 |
Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing | |
Shao, Jingyuan1,2; Chen, Qianjie2,3; Wang, Yuxuan4; Lu, Xiao1; He, Pengzhen5; Sun, Yele6; Shah, Viral2,7; Martin, Randall, V8; Philip, Sajeev9; Song, Shaojie7; Zhao, Yue10; Xie, Zhouqing5; Zhang, Lin1; Alexander, Becky2 | |
2019-05-08 | |
发表期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS
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ISSN | 1680-7316 |
EISSN | 1680-7324 |
出版年 | 2019 |
卷号 | 19期号:9页码:6107-6123 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; USA; Canada |
英文摘要 | Air quality models have not been able to reproduce the magnitude of the observed concentrations of fine particulate matter (PM2.5) during wintertime Chinese haze events. The discrepancy has been at least partly attributed to low biases in modeled sulfate production rates, due to the lack of heterogeneous sulfate production on aerosols in the models. In this study, we explicitly implement four heterogeneous sulfate formation mechanisms into a regional chemical transport model, in addition to gas-phase and incloud sulfate production. We compare the model results with observations of sulfate concentrations and oxygen isotopes, Delta O-17(SO42-), in the winter of 2014-2015, the latter of which is highly sensitive to the relative importance of different sulfate production mechanisms. Model results suggest that heterogeneous sulfate production on aerosols accounts for about 20% of sulfate production in clean and polluted conditions, partially reducing the modeled low bias in sulfate concentrations. Model sensitivity studies in comparison with the Delta O-17(SO42-) observations suggest that heterogeneous sulfate formation is dominated by transition metal ion-catalyzed oxidation of SO2. |
领域 | 地球科学 |
收录类别 | SCI-E |
WOS记录号 | WOS:000467412800005 |
WOS关键词 | FINE-PARTICLE PH ; ATMOSPHERIC SULFATE ; SULFUR-DIOXIDE ; NORTHERN CHINA ; MINERAL DUST ; BOTTOM-UP ; CHEMISTRY ; OXIDATION ; CONSTRAINTS ; NITRATE |
WOS类目 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
WOS研究方向 | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/183176 |
专题 | 地球科学 |
作者单位 | 1.Peking Univ, Sch Phys, Dept Atmospher & Ocean Sci, Lab Climate & Ocean Atmosphere Studies, Beijing 100871, Peoples R China; 2.Univ Washington, Dept Atmospher Sci, Seattle, WA 98195 USA; 3.Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA; 4.Univ Houston, Dept Earth & Atmospher Sci, Houston, TX 77204 USA; 5.Univ Sci & Technol China, Sch Earth & Space Sci, Anhui Prov Key Lab Polar Environm & Global Change, Hefei 230026, Anhui, Peoples R China; 6.Chinese Acad Sci, Inst Atmospher Phys, State Key Lab Atmospher Boundary Phys & Atmospher, Beijing 100029, Peoples R China; 7.Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA; 8.Dalhousie Univ, Dept Phys & Atmospher Sci, Halifax, NS, Canada; 9.NASA, Ames Res Ctr, NASA Postdoctoral Program, Moffett Field, CA 94035 USA; 10.Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China |
推荐引用方式 GB/T 7714 | Shao, Jingyuan,Chen, Qianjie,Wang, Yuxuan,et al. Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2019,19(9):6107-6123. |
APA | Shao, Jingyuan.,Chen, Qianjie.,Wang, Yuxuan.,Lu, Xiao.,He, Pengzhen.,...&Alexander, Becky.(2019).Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing.ATMOSPHERIC CHEMISTRY AND PHYSICS,19(9),6107-6123. |
MLA | Shao, Jingyuan,et al."Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing".ATMOSPHERIC CHEMISTRY AND PHYSICS 19.9(2019):6107-6123. |
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