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Ruthenium isotope vestige of Earth's pre-late-veneer mantle preserved in Archaean rocks 期刊论文
NATURE, 2020, 579 (7798) : 240-+
作者:  Abadie, Valerie;  Kim, Sangman M.;  Lejeune, Thomas;  Palanski, Brad A.;  Ernest, Jordan D.;  Tastet, Olivier;  Voisine, Jordan;  Discepolo, Valentina;  Marietta, Eric, V;  Hawash, Mohamed B. F.;  Ciszewski, Cezary;  Bouziat, Romain;  Panigrahi, Kaushik;  Horwath, Irina;  Zurenski, Matthew A.;  Lawrence, Ian;  Dumaine, Anne;  Yotova, Vania;  Grenier, Jean-Christophe;  Murray, Joseph A.;  Khosla, Chaitan;  Barreiro, Luis B.;  Jabri, Bana
收藏  |  浏览/下载:31/0  |  提交时间:2020/05/13

The accretion of volatile-rich material from the outer Solar System represents a crucial prerequisite for Earth to develop oceans and become a habitable planet(1-4). However, the timing of this accretion remains controversial(5-8). It has been proposed that volatile elements were added to Earth by the late accretion of a late veneer consisting of carbonaceous-chondrite-like material after core formation had ceased(6,9,10). This view could not be reconciled with the ruthenium (Ru) isotope composition of carbonaceous chondrites(5,11), which is distinct from that of the modern mantle(12), or of any known meteorite group(5). As a possible solution, Earth'  s pre-late-veneer mantle could already have contained a fraction of Ru that was not fully extracted by core formation(13). The presence of such pre-late-veneer Ru can only be established if its isotope composition is distinct from that of the modern mantle. Here we report the first high-precision, mass-independent Ru isotope compositions for Eoarchaean ultramafic rocks from southwest Greenland, which display a relative Ru-100 excess of 22 parts per million compared with the modern mantle value. This Ru-100 excess indicates that the source of the Eoarchaean rocks already contained a substantial fraction of Ru before the accretion of the late veneer. By 3.7 billion years ago, the mantle beneath southwest Greenland had not yet fully equilibrated with late accreted material. Otherwise, no Ru isotopic difference relative to the modern mantle would be observed. If constraints from other highly siderophile elements besides Ru are also considered(14), the composition of the modern mantle can only be reconciled if the late veneer contained substantial amounts of carbonaceous-chondrite-like materials with their characteristic Ru-100 deficits. These data therefore relax previous constraints on the late veneer and are consistent with volatile-rich material from the outer Solar System being delivered to Earth during late accretion.


  
Synchrotron infrared spectroscopic evidence of the probable transition to metal hydrogen 期刊论文
NATURE, 2020, 577 (7792) : 631-+
作者:  Zhuang, Zhe;  Yu, Jin-Quan
收藏  |  浏览/下载:25/0  |  提交时间:2020/07/03

Hydrogen has been an essential element in the development of atomic, molecular and condensed matter physics(1). It is predicted that hydrogen should have a metal state(2)  however, understanding the properties of dense hydrogen has been more complex than originally thought, because under extreme conditions the electrons and protons are strongly coupled to each other and ultimately must both be treated as quantum particles(3,4). Therefore, how and when molecular solid hydrogen may transform into a metal is an open question. Although the quest for metal hydrogen has pushed major developments in modern experimental high-pressure physics, the various claims of its observation remain unconfirmed(5-7). Here a discontinuous change of the direct bandgap of hydrogen, from 0.6 electronvolts to below 0.1 electronvolts, is observed near 425 gigapascals. This result is most probably associated with the formation of the metallic state because the nucleus zero-point energy is larger than this lowest bandgap value. Pressures above 400 gigapascals are achieved with the recently developed toroidal diamond anvil cell(8), and the structural changes and electronic properties of dense solid hydrogen at 80 kelvin are probed using synchrotron infrared absorption spectroscopy. The continuous downward shifts of the vibron wavenumber and the direct bandgap with increased pressure point to the stability of phase-III hydrogen up to 425 gigapascals. The present data suggest that metallization of hydrogen proceeds within the molecular solid, in good agreement with previous calculations that capture many-body electronic correlations(9).


  
Value of a Limited Number of Discharge Observations for Improving Regionalization: A Large-Sample Study Across the United States 期刊论文
WATER RESOURCES RESEARCH, 2019, 55 (1) : 363-377
作者:  Pool, S.;  Viviroli, D.;  Seibert, J.
收藏  |  浏览/下载:3/0  |  提交时间:2019/04/09
ungauged basin  regionalization  spatial proximity  attribute similarity  value of data  
Data Assimilation in Density-Dependent Subsurface Flows via Localized Iterative Ensemble Kalman Filter 期刊论文
WATER RESOURCES RESEARCH, 2018, 54 (9) : 6259-6281
作者:  Xia, Chuan-An;  Hu, Bill X.;  Tong, Juxiu;  Guadagnini, Alberto
收藏  |  浏览/下载:5/0  |  提交时间:2019/04/09
variable density flow  value of data  iterative ensemble Kalman filter  ensemble Kalman filter