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The effect of considering polar vortex dynamics in the validation of satellite total ozone observations 期刊论文
ATMOSPHERIC RESEARCH, 2020, 238
作者:  Paschou, Peristera;  Koukouli, Maria-Elissavet;  Balis, Dimitrios;  Lerot, Christophe;  Van Roozendael, Michel
收藏  |  浏览/下载:7/0  |  提交时间:2020/08/18
Total ozone column  GOME2  OMI  Validation  Potential vorticity  
Evaluation of an Improved Convective Triggering Function: Observational Evidence and SCM Tests 期刊论文
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2020, 125 (11)
作者:  Wang, Yi-Chi;  Xie, Shaocheng;  Tang, Shuaiqi;  Lin, Wuyin
收藏  |  浏览/下载:10/0  |  提交时间:2020/08/18
convection trigger  convection  diurnal cycle of precipitation  E3SM  precipitation  single-column model  
Intra-annual variations of regional total column ozone, aerosol optical depth, and water vapor from ground-based, satellite-based and model-based observations 期刊论文
ATMOSPHERIC RESEARCH, 2020, 237
作者:  Nade, Dada P.;  Potdar, Swapnil S.;  Pawar, Rani P.;  Taori, Alok;  Kulkarni, Gourihar;  Siingh, Devendraa;  Pawar, Sunil D.
收藏  |  浏览/下载:8/0  |  提交时间:2020/07/02
Microtops II ozonometer  Total column ozone  Precipitable water content  Aerosol optical depth  
Relationship between solar activity and direct solar irradiance in Madrid (1910-1929) 期刊论文
ATMOSPHERIC RESEARCH, 2020, 235
作者:  Aparicio, A. J. P.;  Gallego, M. C.;  Anton, M.;  Vaquero, J. M.
收藏  |  浏览/下载:5/0  |  提交时间:2020/07/02
Solar activity  Sunspot Number  Direct solar irradiance  Pyrheliometer  Atmospheric column transparency  
Lactonization as a general route to beta-C(sp(3))-H functionalization 期刊论文
NATURE, 2020, 577 (7792) : 656-+
作者:  Washington, Harriet A.
收藏  |  浏览/下载:17/0  |  提交时间:2020/07/03

Functionalization of the beta-C-H bonds of aliphatic acids is emerging as a valuable synthetic disconnection that complements a wide range of conjugate addition reactions(1-5). Despite efforts for beta-C-H functionalization in carbon-carbon and carbon-heteroatom bond-forming reactions, these have numerous crucial limitations, especially for industrial-scale applications, including lack of mono-selectivity, use of expensive oxidants and limited scope(6-13). Notably, the majority of these reactions are incompatible with free aliphatic acids without exogenous directing groups. Considering the challenge of developing C-H activation reactions, it is not surprising that achieving different transformations requires independent catalyst design and directing group optimizations in each case. Here we report a Pd-catalysed beta-C(sp(3))-H lactonization of aliphatic acids enabled by a mono-N-protected beta-amino acid ligand. The highly strained and reactive beta-lactone products are versatile linchpins for the mono-selective installation of diverse alkyl, alkenyl, aryl, alkynyl, fluoro, hydroxyl and amino groups at the beta position of the parent acid, thus providing a route to many carboxylic acids. The use of inexpensive tert-butyl hydrogen peroxide as the oxidant to promote the desired selective reductive elimination from the Pd(IV) centre, as well as the ease of product purification without column chromatography, render this reaction amenable to tonne-scale manufacturing.


  
A Mechanism for the Maintenance of Sharp Tropical Margins 期刊论文
JOURNAL OF THE ATMOSPHERIC SCIENCES, 2020, 77 (4) : 1181-1197
作者:  Masunaga, Hirohiko;  Mapes, Brian E.
收藏  |  浏览/下载:9/0  |  提交时间:2020/07/02
Tropics  Convection  Water vapor  Satellite observations  Single column models  
Perturbation Solution for Four-Stream Infrared Radiative Transfer 期刊论文
JOURNAL OF THE ATMOSPHERIC SCIENCES, 2020, 77 (4) : 1497-1507
作者:  Li, Jiangnan;  Barker, Howard W.
收藏  |  浏览/下载:6/0  |  提交时间:2020/07/02
Radiation budgets  Radiative fluxes  Radiative transfer  Clouds  Single column models  
Analytical Investigation of the Role of Lateral Mixing in the Evolution of Nonprecipitating Cumulus. Part II: Dissolving Stage 期刊论文
JOURNAL OF THE ATMOSPHERIC SCIENCES, 2020, 77 (3) : 911-924
作者:  Pinsky, M.;  Khain, A.
收藏  |  浏览/下载:6/0  |  提交时间:2020/07/02
Clouds  Mixing  Clouds  Cumulus clouds  Single column models  
Ice front blocking of ocean heat transport to an Antarctic ice shelf 期刊论文
NATURE, 2020, 578 (7796) : 568-+
作者:  Alexandrov, Ludmil B.;  Kim, Jaegil;  Haradhvala, Nicholas J.;  Huang, Mi Ni;  Ng, Alvin Wei Tian;  Wu, Yang;  Boot, Arnoud;  Covington, Kyle R.;  Gordenin, Dmitry A.;  Bergstrom, Erik N.;  Islam, S. M. Ashiqul;  Lopez-Bigas, Nuria;  Klimczak, Leszek J.;  McPherson, John R.;  Morganella, Sandro;  Sabarinathan, Radhakrishnan;  Wheeler, David A.;  Mustonen, Ville;  Getz, Gad;  Rozen, Steven G.;  Stratton, Michael R.
收藏  |  浏览/下载:12/0  |  提交时间:2020/05/13

The front of the Getz Ice Shelf in West Antarctica creates an abrupt topographic step that deflects ocean currents, suppressing 70% of the heat delivery to the ice sheet.


Mass loss from the Antarctic Ice Sheet to the ocean has increased in recent decades, largely because the thinning of its floating ice shelves has allowed the outflow of grounded ice to accelerate(1,2). Enhanced basal melting of the ice shelves is thought to be the ultimate driver of change(2,3), motivating a recent focus on the processes that control ocean heat transport onto and across the seabed of the Antarctic continental shelf towards the ice(4-6). However, the shoreward heat flux typically far exceeds that required to match observed melt rates(2,7,8), suggesting that other critical controls exist. Here we show that the depth-independent (barotropic) component of the heat flow towards an ice shelf is blocked by the marked step shape of the ice front, and that only the depth-varying (baroclinic) component, which is typically much smaller, can enter the sub-ice cavity. Our results arise from direct observations of the Getz Ice Shelf system and laboratory experiments on a rotating platform. A similar blocking of the barotropic component may occur in other areas with comparable ice-bathymetry configurations, which may explain why changes in the density structure of the water column have been found to be a better indicator of basal melt rate variability than the heat transported onto the continental shelf(9). Representing the step topography of the ice front accurately in models is thus important for simulating ocean heat fluxes and induced melt rates.


  
Effect of lower stratospheric temperature on total ozone column (TOC) during the ozone depletion and recovery phases 期刊论文
ATMOSPHERIC RESEARCH, 2020, 232
作者:  Ningombam, Shantikumar S.;  Vemareddy, P.;  Song, H-J
收藏  |  浏览/下载:6/0  |  提交时间:2020/07/02
Total ozone column  Equivalent Effective Stratospheric Chlorine  Back-scatter ultraviolet  Statistically significant