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Anthropogenic and biogenic hydrophobic VOCs detected in clouds at the puy de Dome station using Stir Bar Sorptive Extraction: Deviation from the Henry's law prediction 期刊论文
ATMOSPHERIC RESEARCH, 2020, 237
作者:  Wang, Miao;  Perroux, Helene;  Fleuret, Jennifer;  Bianco, Angelica;  Bouvier, Laetitia;  Colomb, Aurelie;  Borbon, Agnes;  Deguillaume, Laurent
收藏  |  浏览/下载:6/0  |  提交时间:2020/07/02
Volatile organic compounds (VOCs)  Cloud  Gas-liquid partitioning  Henry'  s law  PUY station  Stir Bar Sorptive Extraction (SBSE)  
Entanglement-based secure quantum cryptography over 1,120 kilometres 期刊论文
NATURE, 2020
作者:  Paldi, Flora;  Alver, Bonnie;  Robertson, Daniel;  Schalbetter, Stephanie A.;  Kerr, Alastair;  Kelly, David A.;  Baxter, Jonathan;  Neale, Matthew J.;  Marston, Adele L.
收藏  |  浏览/下载:49/0  |  提交时间:2020/07/03

An efficient entanglement-based quantum key distribution is sent from the Micius satellite to two ground observatories 1,120 kilometres apart to establish secure quantum cryptography for the exchange ofquantum keys.


Quantum key distribution (QKD)(1-3)is a theoretically secure way of sharing secret keys between remote users. It has been demonstrated in a laboratory over a coiled optical fibre up to 404 kilometres long(4-7). In the field, point-to-point QKD has been achieved from a satellite to a ground station up to 1,200 kilometres away(8-10). However, real-world QKD-based cryptography targets physically separated users on the Earth, for which the maximum distance has been about 100 kilometres(11,12). The use of trusted relays can extend these distances from across a typical metropolitan area(13-16)to intercity(17)and even intercontinental distances(18). However, relays pose security risks, which can be avoided by using entanglement-based QKD, which has inherent source-independent security(19,20). Long-distance entanglement distribution can be realized using quantum repeaters(21), but the related technology is still immature for practical implementations(22). The obvious alternative for extending the range of quantum communication without compromising its security is satellite-based QKD, but so far satellite-based entanglement distribution has not been efficient(23)enough to support QKD. Here we demonstrate entanglement-based QKD between two ground stations separated by 1,120 kilometres at a finite secret-key rate of 0.12 bits per second, without the need for trusted relays. Entangled photon pairs were distributed via two bidirectional downlinks from the Micius satellite to two ground observatories in Delingha and Nanshan in China. The development of a high-efficiency telescope and follow-up optics crucially improved the link efficiency. The generated keys are secure for realistic devices, because our ground receivers were carefully designed to guarantee fair sampling and immunity to all known side channels(24,25). Our method not only increases the secure distance on the ground tenfold but also increases the practical security of QKD to an unprecedented level.


  
Automated radial synthesis of organic molecules 期刊论文
NATURE, 2020, 579 (7799) : 379-+
作者:  van den Brink, Susanne C.;  Alemany, Anna;  van Batenburg, Vincent;  Moris, Naomi;  Blotenburg, Marloes;  Vivie, Judith;  Baillie-Johnson, Peter;  Nichols, Jennifer;  Sonnen, Katharina F.;  Martinez Arias, Alfonso;  van Oudenaarden, Alexander
收藏  |  浏览/下载:16/0  |  提交时间:2020/07/03

An automated synthesis instrument comprising a series of continuous flow modules that are radially arranged around a central switching station can achieve both linear and convergent syntheses.


Automated synthesis platforms accelerate and simplify the preparation of molecules by removing the physical barriers to organic synthesis. This provides unrestricted access to biopolymers and small molecules via reproducible and directly comparable chemical processes. Current automated multistep syntheses rely on either iterative(1-4) or linear processes(5-9), and require compromises in terms of versatility and the use of equipment. Here we report an approach towards the automated synthesis of small molecules, based on a series of continuous flow modules that are radially arranged around a central switching station. Using this approach, concise volumes can be exposed to any reaction conditions required for a desired transformation. Sequential, non-simultaneous reactions can be combined to perform multistep processes, enabling the use of variable flow rates, reuse of reactors under different conditions, and the storage of intermediates. This fully automated instrument is capable of both linear and convergent syntheses and does not require manual reconfiguration between different processes. The capabilities of this approach are demonstrated by performing optimizations and multistep syntheses of targets, varying concentrations via inline dilutions, exploring several strategies for the multistep synthesis of the anticonvulsant drug rufinamide(10), synthesizing eighteen compounds of two derivative libraries that are prepared using different reaction pathways and chemistries, and using the same reagents to perform metallaphotoredox carbon-nitrogen cross-couplings(11) in a photochemical module-all without instrument reconfiguration.


  
An assessment of global satellite-based precipitation datasets in capturing precipitation extremes: A comparison with observed precipitation dataset in India 期刊论文
INTERNATIONAL JOURNAL OF CLIMATOLOGY, 2019
作者:  Gupta, Vivek;  Jain, Manoj K.;  Singh, Pushpendra K.;  Singh, Vishal
收藏  |  浏览/下载:9/0  |  提交时间:2020/02/17
Climate Hazards Group InfraRed Precipitation with Station  extreme precipitation  Indian Meteorological Department precipitation  Soil Moisture to Rain  Tropical Rainfall Measuring Mission  
Variations in the Intensity and Spatial Extent of Tropical Cyclone Precipitation 期刊论文
GEOPHYSICAL RESEARCH LETTERS, 2019, 46 (23) : 13992-14002
作者:  Touma, Danielle;  Stevenson, Samantha;  Camargo, Suzana J.;  Horton, Daniel E.;  Diffenbaugh, Noah S.
收藏  |  浏览/下载:11/0  |  提交时间:2020/02/17
tropical cyclone precipitation  Atlantic tropical cyclones  station precipitation data  geostatistics  
Urbanization Effect in Regional Temperature Series Based on a Remote Sensing Classification Scheme of Stations 期刊论文
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2019
作者:  Tysa, Suonam Kealdrup;  Ren, Guoyu;  Qin, Yun;  Zhang, Panfeng;  Ren, Yuyu;  Jia, Wenqian;  Wen, Kangmin
收藏  |  浏览/下载:13/0  |  提交时间:2019/11/27
urbanization effect  air temperature  linear trend  remote sensing  station classification  China  
Observed Atmospheric and Surface Variability on Heterogeneous Terrain at the Hectometer Scale and Related Advective Transports 期刊论文
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2019, 124 (16) : 9407-9422
作者:  Simo, Gemma;  Cuxart, Joan;  Jimenez, Maria A.;  Martinez-Villagrasa, Daniel;  Picos, Rodrigo;  Lopez-Grifol, Alvaro;  Marti, Belen
收藏  |  浏览/下载:8/0  |  提交时间:2019/11/27
atmospheric and upper-soil variability  surface energy and water budgets  local thermal advection  station representativeness  humidity advection and evapotranspiration  hectometer scale  
Meteorology and summer net radiation of an Arctic alpine glacier: Svenbreen, Svalbard 期刊论文
INTERNATIONAL JOURNAL OF CLIMATOLOGY, 2019, 39 (10) : 4107-4124
作者:  Malecki, Jakub
收藏  |  浏览/下载:5/0  |  提交时间:2019/11/27
air temperature  automatic weather station  climate  glacier albedo  lapse rate  melt season  mountain environment  
Cluster analysis of tropical cyclones affecting the Taiwan Strait 期刊论文
INTERNATIONAL JOURNAL OF CLIMATOLOGY, 2019, 39 (10) : 3915-3931
作者:  Liu, Deqiang;  Pan, Ning;  Huang, Chuanrong;  Zheng, Jiayu;  He, Chao
收藏  |  浏览/下载:7/0  |  提交时间:2019/11/27
automatic weather station  cluster  fuzzy C-means method  the Taiwan Strait  tropical cyclone  
Joint Inversion of Rayleigh Wave Phase Velocity, Particle Motion, and Teleseismic Body Wave Data for Sedimentary Structures 期刊论文
GEOPHYSICAL RESEARCH LETTERS, 2019, 46 (12) : 6469-6478
作者:  Li, Guoliang;  Niu, Fenglin;  Yang, Yingjie;  Tao, Kai
收藏  |  浏览/下载:6/0  |  提交时间:2019/11/26
sedimentary structures  joint inversion  reverberations removement  subsurface receiver function  single station recording