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Accurate compound-specific C-14 dating of archaeological pottery vessels 期刊论文
NATURE, 2020, 580 (7804) : 506-+
作者:  Yin, Yafei;  Lu, J. Yuyang;  Zhang, Xuechun;  Shao, Wen;  Xu, Yanhui;  Li, Pan;  Hong, Yantao;  Cui, Li;  Shan, Ge;  Tian, Bin;  Zhang, Qiangfeng Cliff;  Shen, Xiaohua
收藏  |  浏览/下载:20/0  |  提交时间:2020/05/13

Pottery is one of the most commonly recovered artefacts from archaeological sites. Despite more than a century of relative dating based on typology and seriation(1), accurate dating of pottery using the radiocarbon dating method has proven extremely challenging owing to the limited survival of organic temper and unreliability of visible residues(2-4). Here we report a method to directly date archaeological pottery based on accelerator mass spectrometry analysis of C-14 in absorbed food residues using palmitic (C-16:0) and stearic (C-18:0) fatty acids purified by preparative gas chromatography(5-8). We present accurate compound-specific radiocarbon determinations of lipids extracted from pottery vessels, which were rigorously evaluated by comparison with dendrochronological dates(9,10) and inclusion in site and regional chronologies that contained previously determined radiocarbon dates on other materials(11-15). Notably, the compound-specific dates from each of the C-16:0 and C-18:0 fatty acids in pottery vessels provide an internal quality control of the results(6) and are entirely compatible with dates for other commonly dated materials. Accurate radiocarbon dating of pottery vessels can reveal: (1) the period of use of pottery  (2) the antiquity of organic residues, including when specific foodstuffs were exploited  (3) the chronology of sites in the absence of traditionally datable materials  and (4) direct verification of pottery typochronologies. Here we used the method to date the exploitation of dairy and carcass products in Neolithic vessels from Britain, Anatolia, central and western Europe, and Saharan Africa.


Using lipid residues absorbed in potsherds, the ages of pottery from various archaeological sites are determined and validated using sites for which the dates are well known from other methods.


  
Ruthenium isotope vestige of Earth's pre-late-veneer mantle preserved in Archaean rocks 期刊论文
NATURE, 2020, 579 (7798) : 240-+
作者:  Abadie, Valerie;  Kim, Sangman M.;  Lejeune, Thomas;  Palanski, Brad A.;  Ernest, Jordan D.;  Tastet, Olivier;  Voisine, Jordan;  Discepolo, Valentina;  Marietta, Eric, V;  Hawash, Mohamed B. F.;  Ciszewski, Cezary;  Bouziat, Romain;  Panigrahi, Kaushik;  Horwath, Irina;  Zurenski, Matthew A.;  Lawrence, Ian;  Dumaine, Anne;  Yotova, Vania;  Grenier, Jean-Christophe;  Murray, Joseph A.;  Khosla, Chaitan;  Barreiro, Luis B.;  Jabri, Bana
收藏  |  浏览/下载:31/0  |  提交时间:2020/05/13

The accretion of volatile-rich material from the outer Solar System represents a crucial prerequisite for Earth to develop oceans and become a habitable planet(1-4). However, the timing of this accretion remains controversial(5-8). It has been proposed that volatile elements were added to Earth by the late accretion of a late veneer consisting of carbonaceous-chondrite-like material after core formation had ceased(6,9,10). This view could not be reconciled with the ruthenium (Ru) isotope composition of carbonaceous chondrites(5,11), which is distinct from that of the modern mantle(12), or of any known meteorite group(5). As a possible solution, Earth'  s pre-late-veneer mantle could already have contained a fraction of Ru that was not fully extracted by core formation(13). The presence of such pre-late-veneer Ru can only be established if its isotope composition is distinct from that of the modern mantle. Here we report the first high-precision, mass-independent Ru isotope compositions for Eoarchaean ultramafic rocks from southwest Greenland, which display a relative Ru-100 excess of 22 parts per million compared with the modern mantle value. This Ru-100 excess indicates that the source of the Eoarchaean rocks already contained a substantial fraction of Ru before the accretion of the late veneer. By 3.7 billion years ago, the mantle beneath southwest Greenland had not yet fully equilibrated with late accreted material. Otherwise, no Ru isotopic difference relative to the modern mantle would be observed. If constraints from other highly siderophile elements besides Ru are also considered(14), the composition of the modern mantle can only be reconciled if the late veneer contained substantial amounts of carbonaceous-chondrite-like materials with their characteristic Ru-100 deficits. These data therefore relax previous constraints on the late veneer and are consistent with volatile-rich material from the outer Solar System being delivered to Earth during late accretion.


  
Regulation and regenerative eco-innovation: the case of extracted materials in the UK 期刊论文
ECOLOGICAL ECONOMICS, 2019, 160: 38-51
作者:  Dewick, Paul;  Maytorena-Sanchez, Eunice;  Winch, Graham
收藏  |  浏览/下载:8/0  |  提交时间:2019/11/26
Regenerative eco-innovation  Regulation  Roots of eco-innovation  Built environment  Extracted materials