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Observations of grain-boundary phase transformations in an elemental metal 期刊论文
NATURE, 2020, 579 (7799) : 375-+
作者:  Valente, Luis;  Phillimore, Albert B.;  Melo, Martim;  Warren, Ben H.;  Clegg, Sonya M.;  Havenstein, Katja;  Tiedemann, Ralph;  Illera, Juan Carlos;  Thebaud, Christophe;  Aschenbach, Tina;  Etienne, Rampal S.
收藏  |  浏览/下载:31/0  |  提交时间:2020/07/03

Atomic-resolution observations combined with simulations show that grain boundaries within elemental copper undergo temperature-induced solid-state phase transformation to different structures  grain boundary phases can also coexist and are kinetically trapped structures.


The theory of grain boundary (the interface between crystallites, GB) structure has a long history(1) and the concept of GBs undergoing phase transformations was proposed 50 years ago(2,3). The underlying assumption was that multiple stable and metastable states exist for different GB orientations(4-6). The terminology '  complexion'  was recently proposed to distinguish between interfacial states that differ in any equilibrium thermodynamic property(7). Different types of complexion and transitions between complexions have been characterized, mostly in binary or multicomponent systems(8-19). Simulations have provided insight into the phase behaviour of interfaces and shown that GB transitions can occur in many material systems(20-24). However, the direct experimental observation and transformation kinetics of GBs in an elemental metal have remained elusive. Here we demonstrate atomic-scale GB phase coexistence and transformations at symmetric and asymmetric [111 over bar ] tilt GBs in elemental copper. Atomic-resolution imaging reveals the coexistence of two different structures at sigma 19b GBs (where sigma 19 is the density of coincident sites and b is a GB variant), in agreement with evolutionary GB structure search and clustering analysis(21,25,26). We also use finite-temperature molecular dynamics simulations to explore the coexistence and transformation kinetics of these GB phases. Our results demonstrate how GB phases can be kinetically trapped, enabling atomic-scale room-temperature observations. Our work paves the way for atomic-scale in situ studies of metallic GB phase transformations, which were previously detected only indirectly(9,15,27-29), through their influence on abnormal grain growth, non-Arrhenius-type diffusion or liquid metal embrittlement.


  
A meta-analysis of temperature sensitivity as a microbial trait 期刊论文
GLOBAL CHANGE BIOLOGY, 2018, 24 (9) : 4211-4224
作者:  Alster, Charlotte J.;  Weller, Zachary D.;  von Fischer, Joseph C.
收藏  |  浏览/下载:19/0  |  提交时间:2019/04/09
activation energy  Arrhenius  ecological theory  functional traits  macromolecular rate theory  microbial trait  Q10  
The responses of microbial temperature relationships to seasonal change and winter warming in a temperate grassland 期刊论文
GLOBAL CHANGE BIOLOGY, 2018, 24 (8) : 3357-3367
作者:  Birgander, Johanna;  Olsson, Pal Axel;  Rousk, Johannes
收藏  |  浏览/下载:19/0  |  提交时间:2019/04/09
Arrhenius and Ratkowsky temperature relationships  experimental warming  temperature dependence  temperature sensitivity (Q(10))  winter warming  
Improving models of photosynthetic thermal acclimation: Which parameters are most important and how many should be modified? 期刊论文
GLOBAL CHANGE BIOLOGY, 2018, 24 (4) : 1580-1598
作者:  Stinziano, Joseph R.;  Way, Danielle A.;  Bauerle, William L.
收藏  |  浏览/下载:21/0  |  提交时间:2019/04/09
climate change  Eddy covariance  J(max)  modified Arrhenius equation  scaling  seasonality  temperature  V-cmax  
Macromolecular rate theory (MMRT) provides a thermodynamics rationale to underpin the convergent temperature response in plant leaf respiration 期刊论文
GLOBAL CHANGE BIOLOGY, 2018, 24 (4) : 1538-1547
作者:  Liang, Liyin L.;  39;Sullivan, Odhran S.
收藏  |  浏览/下载:13/0  |  提交时间:2019/04/09
Arrhenius  climate change  heat capacity  leaf respiration  macromolecular rate theory  temperature response  thermodynamics  
An alternative explanation for global trends in thermal tolerance 期刊论文
ECOLOGY LETTERS, 2017, 20 (1)
作者:  Payne, Nicholas L.;  Smith, James A.
收藏  |  浏览/下载:19/0  |  提交时间:2019/04/09
Activation energy  Arrhenius-Boltzmann  climate change  Janzen'  s hypothesis  macroecology  mountain passes  MTE  polar  Rapoport'  s rule  thermal specialist