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Observations of grain-boundary phase transformations in an elemental metal 期刊论文
NATURE, 2020, 579 (7799) : 375-+
作者:  Valente, Luis;  Phillimore, Albert B.;  Melo, Martim;  Warren, Ben H.;  Clegg, Sonya M.;  Havenstein, Katja;  Tiedemann, Ralph;  Illera, Juan Carlos;  Thebaud, Christophe;  Aschenbach, Tina;  Etienne, Rampal S.
收藏  |  浏览/下载:17/0  |  提交时间:2020/07/03

Atomic-resolution observations combined with simulations show that grain boundaries within elemental copper undergo temperature-induced solid-state phase transformation to different structures  grain boundary phases can also coexist and are kinetically trapped structures.


The theory of grain boundary (the interface between crystallites, GB) structure has a long history(1) and the concept of GBs undergoing phase transformations was proposed 50 years ago(2,3). The underlying assumption was that multiple stable and metastable states exist for different GB orientations(4-6). The terminology '  complexion'  was recently proposed to distinguish between interfacial states that differ in any equilibrium thermodynamic property(7). Different types of complexion and transitions between complexions have been characterized, mostly in binary or multicomponent systems(8-19). Simulations have provided insight into the phase behaviour of interfaces and shown that GB transitions can occur in many material systems(20-24). However, the direct experimental observation and transformation kinetics of GBs in an elemental metal have remained elusive. Here we demonstrate atomic-scale GB phase coexistence and transformations at symmetric and asymmetric [111 over bar ] tilt GBs in elemental copper. Atomic-resolution imaging reveals the coexistence of two different structures at sigma 19b GBs (where sigma 19 is the density of coincident sites and b is a GB variant), in agreement with evolutionary GB structure search and clustering analysis(21,25,26). We also use finite-temperature molecular dynamics simulations to explore the coexistence and transformation kinetics of these GB phases. Our results demonstrate how GB phases can be kinetically trapped, enabling atomic-scale room-temperature observations. Our work paves the way for atomic-scale in situ studies of metallic GB phase transformations, which were previously detected only indirectly(9,15,27-29), through their influence on abnormal grain growth, non-Arrhenius-type diffusion or liquid metal embrittlement.


  
Extinction filters mediate the global effects of habitat fragmentation on animals 期刊论文
SCIENCE, 2019, 366 (6470) : 1236-+
作者:  Betts, Matthew G.;  Wolf, Christopher;  Pfeifer, Marion;  Banks-Leite, Cristina;  Arroyo-Rodriguez, Victor;  Ribeiro, Danilo Bandini;  Barlow, Jos;  Eigenbrod, Felix;  Faria, Deborah;  Fletcher, Robert J., Jr.;  Hadley, Adam S.;  Hawes, Joseph E.;  Holt, Robert D.;  Klingbeil, Brian;  Kormann, Urs;  Lens, Luc;  Levi, Taal;  Medina-Rangel, Guido F.;  Melles, Stephanie L.;  Mezger, Dirk;  Morante-Filho, Jose Carlos;  Orme, C. David L.;  Peres, Carlos A.;  Phalan, Benjamin T.;  Pidgeon, Anna;  Possingham, Hugh;  Ripple, William J.;  Slade, Eleanor M.;  Somarriba, Eduardo;  Tobias, Joseph A.;  Tylianakis, Jason M.;  Nicolas Urbina-Cardona, J.;  Valente, Jonathon J.;  Watling, James I.;  Wells, Konstans;  Wearn, Oliver R.;  Wood, Eric;  Young, Richard;  Ewers, Robert M.
收藏  |  浏览/下载:33/0  |  提交时间:2020/02/17
Biological control of Gonipterus: Uncovering the associations between eucalypts, weevils and parasitoids in their native range 期刊论文
FOREST ECOLOGY AND MANAGEMENT, 2019, 443: 106-116
作者:  Garcia, Andre;  Allen, Geoff R.;  Oberprieler, Rolf G.;  Ramos, Ana Paula;  Valente, Carlos;  Reis, Ana;  Franco, Jose Carlos;  Branco, Manuela
收藏  |  浏览/下载:7/0  |  提交时间:2019/11/27
Eucalyptus  Anaphes inexpectatus  A. nitens  A. tasmaniae  Gonipterus platensis  Host associations  
Economic Outcome of Classical Biological Control: A Case Study on the Eucalyptus Snout Beetle, Gonipterus platensis, and the Parasitoid Anaphes nitens 期刊论文
ECOLOGICAL ECONOMICS, 2018, 149: 40-47
作者:  Valente, Carlos;  Goncalves, Catarina I.;  Monteiro, Fernanda;  Gaspar, Joao;  Silva, Margarida;  Sottomayor, Miguel;  Paiva, Maria Rosa;  Branco, Manuela
收藏  |  浏览/下载:10/0  |  提交时间:2019/04/09
Eucalyptus Weevil  Cost-Benefit Analysis  Biological Invasions  Pest Management  Natural Enemy  Defoliation