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Observations of grain-boundary phase transformations in an elemental metal 期刊论文
NATURE, 2020, 579 (7799) : 375-+
作者:  Valente, Luis;  Phillimore, Albert B.;  Melo, Martim;  Warren, Ben H.;  Clegg, Sonya M.;  Havenstein, Katja;  Tiedemann, Ralph;  Illera, Juan Carlos;  Thebaud, Christophe;  Aschenbach, Tina;  Etienne, Rampal S.
收藏  |  浏览/下载:16/0  |  提交时间:2020/07/03

Atomic-resolution observations combined with simulations show that grain boundaries within elemental copper undergo temperature-induced solid-state phase transformation to different structures  grain boundary phases can also coexist and are kinetically trapped structures.


The theory of grain boundary (the interface between crystallites, GB) structure has a long history(1) and the concept of GBs undergoing phase transformations was proposed 50 years ago(2,3). The underlying assumption was that multiple stable and metastable states exist for different GB orientations(4-6). The terminology '  complexion'  was recently proposed to distinguish between interfacial states that differ in any equilibrium thermodynamic property(7). Different types of complexion and transitions between complexions have been characterized, mostly in binary or multicomponent systems(8-19). Simulations have provided insight into the phase behaviour of interfaces and shown that GB transitions can occur in many material systems(20-24). However, the direct experimental observation and transformation kinetics of GBs in an elemental metal have remained elusive. Here we demonstrate atomic-scale GB phase coexistence and transformations at symmetric and asymmetric [111 over bar ] tilt GBs in elemental copper. Atomic-resolution imaging reveals the coexistence of two different structures at sigma 19b GBs (where sigma 19 is the density of coincident sites and b is a GB variant), in agreement with evolutionary GB structure search and clustering analysis(21,25,26). We also use finite-temperature molecular dynamics simulations to explore the coexistence and transformation kinetics of these GB phases. Our results demonstrate how GB phases can be kinetically trapped, enabling atomic-scale room-temperature observations. Our work paves the way for atomic-scale in situ studies of metallic GB phase transformations, which were previously detected only indirectly(9,15,27-29), through their influence on abnormal grain growth, non-Arrhenius-type diffusion or liquid metal embrittlement.


  
Factors driving the seasonal and hourly variability of sea-spray aerosol number in the North Atlantic 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (41) : 20309-20314
作者:  Saliba, Georges;  Chen, Chia-Li;  Lewis, Savannah;  Russell, Lynn M.;  Rivellini, Laura-Helena;  Lee, Alex K. Y.;  Quinn, Patricia K.;  Bates, Timothy S.;  Haentjens, Nils;  Boss, Emmanuel S.;  Karp-Boss, Lee;  Baetge, Nicholas;  Carlson, Craig A.;  Behrenfeld, Michael J.
收藏  |  浏览/下载:7/0  |  提交时间:2019/11/27
NAAMES  sea spray aerosol  phytoplankton bloom  radiative impacts  
Clathrate hydrates in interstellar environment 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (5) : 1526-1531
作者:  Ghosh, Jyotirmoy;  Methikkalam, Rabin Rajan J.;  Bhuin, Radha Gobinda;  Ragupathy, Gopi;  Choudhary, Nilesh;  Kumar, Rajnish;  Pradeep, Thalappil
收藏  |  浏览/下载:2/0  |  提交时间:2019/11/27
clathrate hydrate  interstellar medium  ISM  ultra-high vacuum  amorphous solid water  
Supraglacial lake drainage at a fast-flowing Greenlandic outlet glacier 期刊论文
Proceedings of the National Academy of Sciences of the United States of America, 2019, 116 (51) : 25468-25477
作者:  Thomas R. Chudley;  Poul Christoffersen;  Samuel H. Doyle;  Marion Bougamont;  Charlotte M. Schoonman;  Bryn Hubbard;  and Mike R. James
收藏  |  浏览/下载:6/0  |  提交时间:2020/04/16
Greenland  glaciology  ice sheets  lakes  hydrology  
Anthropogenic enhancements to production of highly oxygenated molecules from autoxidation 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (14) : 6641-6646
作者:  Pye, Havala O. T.;  39;Ambro, Emma L.
收藏  |  浏览/下载:8/0  |  提交时间:2019/11/27
autoxidation  SOA  monoterpenes  PM2.5  aerosol  
Episodic organic carbon fluxes from surface ocean to abyssal depths during long-term monitoring in NE Pacific 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2018, 115 (48) : 12235-12240
作者:  Smith, Kenneth L., Jr.;  Ruhl, Henry A.;  Huffard, Christine L.;  Messie, Monique;  Kahru, Mati
收藏  |  浏览/下载:5/0  |  提交时间:2019/11/27
abyssal community  carbon budget  carbon flux  
Saturn's magnetic field revealed by the Cassini Grand Finale 期刊论文
SCIENCE, 2018, 362 (6410) : 46-+
作者:  Dougherty, Michele K.;  Cao, Hao;  Khurana, Krishan K.;  Hunt, Gregory J.;  Provan, Gabrielle;  Kellock, Stephen;  Burton, Marcia E.;  Burk, Thomas A.;  Bunce, Emma J.;  Cowley, Stanley W. H.;  Kivelson, Margaret G.;  Russell, Christopher T.;  Southwood, David J.
收藏  |  浏览/下载:6/0  |  提交时间:2019/11/27
Role of elemental carbon in the photochemical aging of soot 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2018, 115 (30) : 7717-7722
作者:  Li, Meng;  Bao, Fengxia;  Zhang, Yue;  Song, Wenjing;  Chen, Chuncheng;  Zhao, Jincai
收藏  |  浏览/下载:6/0  |  提交时间:2019/11/27
soot  photochemistry  aging  elemental carbon  
The South Asian monsoon-pollution pump and purifier 期刊论文
SCIENCE, 2018, 361 (6399) : 270-+
作者:  Lelieveld, J.;  Bourtsoukidis, E.;  Bruehl, C.;  Fischer, H.;  Fuchs, H.;  Harder, H.;  Hofzumahaus, A.;  Holland, F.;  Marno, D.;  Neumaier, M.;  Pozzer, A.;  Schlager, H.;  Williams, J.;  Zahn, A.;  Ziereis, H.
收藏  |  浏览/下载:8/0  |  提交时间:2019/11/27
Multiple generations of grain aggregation in different environments preceded solar system body formation 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2018, 115 (26) : 6608-6613
作者:  Ishii, Hope A.;  Bradley, John P.;  Bechtel, Hans A.;  Brownlee, Donald E.;  Bustillo, Karen C.;  Ciston, James;  Cuzzi, Jeffrey N.;  Floss, Christine;  Joswiak, David J.
收藏  |  浏览/下载:7/0  |  提交时间:2019/11/27
dust accretion  solar system origin  interstellar dust  cosmic dust