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Ice retreat in Wilkes Basin of East Antarctica during a warm interglacial 期刊论文
NATURE, 2020, 583 (7817) : 554-+
作者:  T. Blackburn;  G. H. Edwards;  S. Tulaczyk;  M. Scudder;  G. Piccione;  B. Hallet;  N. McLean;  J. C. Zachos;  B. Cheney;  J. T. Babbe
收藏  |  浏览/下载:21/0  |  提交时间:2020/08/09

Uranium isotopes in subglacial precipitates from the Wilkes Basin of the East Antarctic Ice Sheet reveal ice retreat during a warm Pleistocene interglacial period about 400,000 years ago.


Efforts to improve sea level forecasting on a warming planet have focused on determining the temperature, sea level and extent of polar ice sheets during Earth'  s past interglacial warm periods(1-3). About 400,000 years ago, during the interglacial period known as Marine Isotopic Stage 11 (MIS11), the global temperature was 1 to 2 degrees Celsius greater(2)and sea level was 6 to 13 metres higher(1,3). Sea level estimates in excess of about 10 metres, however, have been discounted because these require a contribution from the East Antarctic Ice Sheet(3), which has been argued to have remained stable for millions of years before and includes MIS11(4,5). Here we show how the evolution of(234)U enrichment within the subglacial waters of East Antarctica recorded the ice sheet'  s response to MIS11 warming. Within the Wilkes Basin, subglacial chemical precipitates of opal and calcite record accumulation of(234)U (the product of rock-water contact within an isolated subglacial reservoir) up to 20 times higher than that found in marine waters. The timescales of(234)U enrichment place the inception of this reservoir at MIS11. Informed by the(234)U cycling observed in the Laurentide Ice Sheet, where(234)U accumulated during periods of ice stability(6)and was flushed to global oceans in response to deglaciation(7), we interpret our East Antarctic dataset to represent ice loss within the Wilkes Basin at MIS11. The(234)U accumulation within the Wilkes Basin is also observed in the McMurdo Dry Valleys brines(8-10), indicating(11)that the brine originated beneath the adjacent East Antarctic Ice Sheet. The marine origin of brine salts(10)and bacteria(12)implies that MIS11 ice loss was coupled with marine flooding. Collectively, these data indicate that during one of the warmest Pleistocene interglacials, the ice sheet margin at the Wilkes Basin retreated to near the precipitate location, about 700 kilometres inland from the current position of the ice margin, which-assuming current ice volumes-would have contributed about 3 to 4 metres(13)to global sea levels.


  
Pleistocene lakes and paleohydrologic environments of the Tecopa basin, California: Constraints on the drainage integration of the Amargosa River 期刊论文
GEOLOGICAL SOCIETY OF AMERICA BULLETIN, 2020, 132 (7-8) : 1537-1565
作者:  Reheis, Marith C.;  Caskey, John;  Bright, Jordon;  Paces, James B.;  Mahan, Shannon A.;  Wan, Elmira
收藏  |  浏览/下载:10/0  |  提交时间:2020/08/18
300,000 yr history of water-table fluctuations at Wind Cave, South Dakota, USA-Scale, timing, and groundwater mixing in the Madison Aquifer 期刊论文
GEOLOGICAL SOCIETY OF AMERICA BULLETIN, 2020, 132 (7-8) : 1447-1468
作者:  Paces, James B.;  Palmer, Margaret, V;  Palmer, Arthur N.;  Long, Andrew J.;  Emmons, Matthew P.
收藏  |  浏览/下载:10/0  |  提交时间:2020/08/18
Persistent global marine euxinia in the early Silurian 期刊论文
NATURE COMMUNICATIONS, 2020, 11 (1)
作者:  Stockey, Richard G.;  Cole, Devon B.;  Planavsky, Noah J.;  Loydell, David K.;  Fryda, Jiri;  Sperling, Erik A.
收藏  |  浏览/下载:5/0  |  提交时间:2020/05/13
Palaeoproterozoic oxygenated oceans following the Lomagundi-Jatuli Event 期刊论文
NATURE GEOSCIENCE, 2020, 13 (4) : 302-+
作者:  Mand, Kaarel;  Lalonde, Stefan V.;  Robbins, Leslie J.;  Thoby, Marie;  Paiste, Kart;  Kreitsmann, Timmu;  Paiste, Paarn;  Reinhard, Christopher T.;  Romashkin, Alexandr E.;  Planavsky, Noah J.;  Kirsimae, Kalle;  Lepland, Aivo;  Konhauser, Kurt O.
收藏  |  浏览/下载:9/0  |  提交时间:2020/05/13
U-233/U-236 signature allows to distinguish environmental emissions of civil nuclear industry from weapons fallout 期刊论文
NATURE COMMUNICATIONS, 2020, 11 (1)
作者:  Hain, K.;  Steier, P.;  Froehlich, M. B.;  Golser, R.;  Hou, X.;  Lachner, J.;  Nomura, T.;  Qiao, J.;  Quinto, F.;  Sakaguchi, A.
收藏  |  浏览/下载:8/0  |  提交时间:2020/05/13
Paleohydrology of southwest Nevada (USA) based on groundwater U-234/U-238 over the past 475 k.y. 期刊论文
GEOLOGICAL SOCIETY OF AMERICA BULLETIN, 2020, 132 (3-4) : 793-802
作者:  Wendt, Kathleen A.;  Pythoud, Mathieu;  Moseley, Gina E.;  Dublyansky, Yuri, V;  Edwards, R. Lawrence;  Spoetl, Christoph
收藏  |  浏览/下载:8/0  |  提交时间:2020/07/02
Chiral superconductivity in heavy-fermion metal UTe2 期刊论文
NATURE, 2020, 579 (7800) : 523-527
作者:  Chica, Daniel G.;  He, Yihui;  McCall, Kyle M.;  Chung, Duck Young;  Pak, Rahmi O.;  Trimarchi, Giancarlo;  Liu, Zhifu;  De Lurgio, Patrick M.;  Wessels, Bruce W.;  Kanatzidis, Mercouri G.
收藏  |  浏览/下载:45/0  |  提交时间:2020/07/03

Scanning tunnelling microscopy and spectroscopy measurements show chiral edge states inside the superconducting gap of the heavy-fermion superconductor UTe2, indicating the presence of chiral spin-triplet superconductivity.


Spin-triplet superconductors are condensates of electron pairs with spin 1 and an odd-parity wavefunction(1). An interesting manifestation of triplet pairing is the chiral p-wave state, which is topologically non-trivial and provides a natural platform for realizing Majorana edge modes(2,3). However, triplet pairing is rare in solid-state systems and has not been unambiguously identified in any bulk compound so far. Given that pairing is usually mediated by ferromagnetic spin fluctuations, uranium-based heavy-fermion systems containing f-electron elements, which can harbour both strong correlations and magnetism, are considered ideal candidates for realizing spin-triplet superconductivity(4). Here we present scanning tunnelling microscopy studies of the recently discovered heavy-fermion superconductor UTe2, which has a superconducting transition temperature of 1.6 kelvin(5). We find signatures of coexisting Kondo effect and superconductivity that show competing spatial modulations within one unit cell. Scanning tunnelling spectroscopy at step edges reveals signatures of chiral in-gap states, which have been predicted to exist at the boundaries of topological superconductors. Combined with existing data that indicate triplet pairing in UTe2, the presence of chiral states suggests that UTe2 is a strong candidate for chiral-triplet topological superconductivity.


  
Actinide 2-metallabiphenylenes that satisfy Huckel's rule 期刊论文
NATURE, 2020, 578 (7796) : 563-+
作者:  Achar, Yathish Jagadheesh;  Adhil, Mohamood;  Choudhary, Ramveer;  Gilbert, Nick;  Foiani, Marco
收藏  |  浏览/下载:8/0  |  提交时间:2020/07/03

Aromaticity and antiaromaticity, as defined by Huckel'  s rule, are key ideas in organic chemistry, and are both exemplified in biphenylene(1-3)-a molecule that consists of two benzene rings joined by a four-membered ring at its core. Biphenylene analogues in which one of the benzene rings has been replaced by a different (4n + 2) pi-electron system have so far been associated only with organic compounds(4,5). In addition, efforts to prepare a zirconabiphenylene compound resulted in the isolation of a bis(alkyne) zirconocene complex instead(6). Here we report the synthesis and characterization of, to our knowledge, the first 2-metallabiphenylene compounds. Single-crystal X-ray diffraction studies reveal that these complexes have nearly planar, 11-membered metallatricycles with metrical parameters that compare well with those reported for biphenylene. Nuclear magnetic resonance spectroscopy, in addition to nucleus-independent chemical shift calculations, provides evidence that these complexes contain an antiaromatic cyclobutadiene ring and an aromatic benzene ring. Furthermore, spectroscopic evidence, Kohn-Sham molecular orbital compositions and natural bond orbital calculations suggest covalency and delocalization of the uranium f(2) electrons with the carbon-containing ligand.


The synthesis of uranium- and thorium-containing metallabiphenylenes demonstrates the ability of the actinides to stabilize aromatic/antiaromatic structures where transition metals have failed.


  
Earth's earliest granitoids are crystal-rich magma reservoirs tapped by silicic eruptions 期刊论文
NATURE GEOSCIENCE, 2020, 13 (2) : 163-+
作者:  Laurent, Oscar;  Bjoernsen, Jana;  Wotzlaw, Joern-Frederik;  Bretscher, Simone;  Silva, Manuel Pimenta;  Moyen, Jean-Francois;  Ulmer, Peter;  Bachmann, Olivier
收藏  |  浏览/下载:9/0  |  提交时间:2020/05/13