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Observations of grain-boundary phase transformations in an elemental metal 期刊论文
NATURE, 2020, 579 (7799) : 375-+
作者:  Valente, Luis;  Phillimore, Albert B.;  Melo, Martim;  Warren, Ben H.;  Clegg, Sonya M.;  Havenstein, Katja;  Tiedemann, Ralph;  Illera, Juan Carlos;  Thebaud, Christophe;  Aschenbach, Tina;  Etienne, Rampal S.
收藏  |  浏览/下载:16/0  |  提交时间:2020/07/03

Atomic-resolution observations combined with simulations show that grain boundaries within elemental copper undergo temperature-induced solid-state phase transformation to different structures  grain boundary phases can also coexist and are kinetically trapped structures.


The theory of grain boundary (the interface between crystallites, GB) structure has a long history(1) and the concept of GBs undergoing phase transformations was proposed 50 years ago(2,3). The underlying assumption was that multiple stable and metastable states exist for different GB orientations(4-6). The terminology '  complexion'  was recently proposed to distinguish between interfacial states that differ in any equilibrium thermodynamic property(7). Different types of complexion and transitions between complexions have been characterized, mostly in binary or multicomponent systems(8-19). Simulations have provided insight into the phase behaviour of interfaces and shown that GB transitions can occur in many material systems(20-24). However, the direct experimental observation and transformation kinetics of GBs in an elemental metal have remained elusive. Here we demonstrate atomic-scale GB phase coexistence and transformations at symmetric and asymmetric [111 over bar ] tilt GBs in elemental copper. Atomic-resolution imaging reveals the coexistence of two different structures at sigma 19b GBs (where sigma 19 is the density of coincident sites and b is a GB variant), in agreement with evolutionary GB structure search and clustering analysis(21,25,26). We also use finite-temperature molecular dynamics simulations to explore the coexistence and transformation kinetics of these GB phases. Our results demonstrate how GB phases can be kinetically trapped, enabling atomic-scale room-temperature observations. Our work paves the way for atomic-scale in situ studies of metallic GB phase transformations, which were previously detected only indirectly(9,15,27-29), through their influence on abnormal grain growth, non-Arrhenius-type diffusion or liquid metal embrittlement.


  
Depositional interpretation and sequence stratigraphic control on reservoir quality and distribution in the Meramecian Sooner trend Anadarko Basin, Canadian, and Kingfisher Counties (STACK) play, Anadarko Basin, Oklahoma, United States 期刊论文
AAPG BULLETIN, 2020, 104 (2) : 357-386
作者:  Price, Buddy J.;  Pollack, Andrew C.;  Lamb, Alex P.;  Peryam, Tom C.;  Anderson, Jim R.
收藏  |  浏览/下载:6/0  |  提交时间:2020/05/13
Geochemical constraints on the origins of calcite cements and their impacts on reservoir heterogeneities: A case study on tight oil sandstones of the Upper Triassic Yanchang Formation, southwestern Ordos Basin, China 期刊论文
AAPG BULLETIN, 2019, 103 (10) : 2447-2485
作者:  Xi, Kelai;  Cao, Yingchang;  Liu, Keyu;  Wu, Songtao;  Yuan, Guanghui;  Zhu, Rukai;  Zhao, Yiwei;  Hellevang, Helge
收藏  |  浏览/下载:6/0  |  提交时间:2019/11/27
An evolutionary perspective on immunometabolism 期刊论文
SCIENCE, 2019, 363 (6423) : 140-140
作者:  Wang, Andrew;  Luan, Harding H.;  Medzhitov, Ruslan
收藏  |  浏览/下载:5/0  |  提交时间:2019/11/27
In situ measurement of cesium-137 contamination in fruits from the northern Marshall Islands 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (31) : 15414-15419
作者:  Topping, Carlisle E. W.;  Abella, Maveric K. I. L.;  Berkowitz, Michael E.;  Molina, Monica Rouco;  Nikolic-Hughes, Ivana;  Hughes, Emlyn W.;  Ruderman, Malvin A.
收藏  |  浏览/下载:2/0  |  提交时间:2019/11/27
Marshall Islands  food  radiation  cesium-137  Bikini  
Earth's radiative imbalance from the Last Glacial Maximum to the present 期刊论文
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (30) : 14881-14886
作者:  Baggenstos, Daniel;  Haberli, Marcel;  Schmitt, Jochen;  Shackleton, Sarah A.;  Birner, Benjamin;  Severinghaus, Jeffrey P.;  Kellerhals, Thomas;  Fischer, Hubertus
收藏  |  浏览/下载:6/0  |  提交时间:2019/11/27
paleoclimate  deglaciation  noble gases  energy budget  ice cores  
A gamma-ray determination of the Universe's star formation history 期刊论文
SCIENCE, 2018, 362 (6418) : 1031-+
作者:  Abdollahi, S.;  39;Ammando, F.
收藏  |  浏览/下载:2/0  |  提交时间:2019/11/27
Energy: A Human History 期刊论文
SCIENCE, 2018, 360 (6393) : 1062-1063
作者:  McGuffie, Joshua
收藏  |  浏览/下载:0/0  |  提交时间:2019/11/27
THE REALIST Vaclav Smil looks to history for the future of energy. What he sees is sobering 期刊论文
SCIENCE, 2018, 359 (6382) : 1320-1324
作者:  Voosen, Paul
收藏  |  浏览/下载:0/0  |  提交时间:2019/11/27
Three deep resource plays in the San Joaquin Valley compared with the Bakken Formation 期刊论文
AAPG BULLETIN, 2018, 102 (2) : 195-243
作者:  Larue, D. K.;  Smithard, M.;  Mercer, M.
收藏  |  浏览/下载:0/0  |  提交时间:2019/04/09