资源环境科技发展态势分析平台

Globally distributed kimberlites with broadly chondritic initial ¹⁴³Nd-¹⁷⁶Hf isotopic systematics may be derived from a chemically homogenous, relatively primitive mantle source that remained isolated from the convecting mantle for much of the Earth’s history. To assess whether this putative reservoir may have preserved remnants of an early Earth process, we report ¹⁸²W/¹⁸⁴W and ¹⁴²Nd/¹⁴⁴Nd data for “primitive” kimberlites from 10 localities worldwide, ranging in age from 1,153 to 89 Ma. Most are characterized by homogeneous μ¹⁸²W and μ¹⁴²Nd values averaging −5.9 ± 3.6 ppm (2SD, n = 13) and +2.7 ± 2.9 ppm (2SD, n = 6), respectively. The remarkably uniform yet modestly negative μ¹⁸²W values, coupled with chondritic to slightly suprachondritic initial ¹⁴³Nd/¹⁴⁴Nd and ¹⁷⁶Hf/¹⁷⁷Hf ratios over a span of nearly 1,000 Mya, provides permissive evidence that these kimberlites were derived from one or more long-lived, early formed mantle reservoirs. Possible causes for negative μ¹⁸²W values among these kimberlites include the transfer of W with low μ¹⁸²W from the core to the mantle source reservoir(s), creation of the source reservoir(s) as a result of early silicate fractionation, or an overabundance of late-accreted materials in the source reservoir(s). By contrast, two younger kimberlites emplaced at 72 and 52 Ma and characterized by distinctly subchondritic initial ¹⁷⁶Hf/¹⁷⁷Hf and ¹⁴³Nd/¹⁴⁴Nd have μ¹⁸²W values consistent with the modern upper mantle. These isotopic compositions may reflect contamination of the ancient kimberlite source by recycled crustal components with μ¹⁸²W ≥ 0.