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DOI | 10.1002/2017JD027111 |
Evaporation Kinetics of Polyol Droplets: Determination of Evaporation Coefficients and Diffusion Constants | |
Su, Yong-Yang1; Marsh, Aleksandra2; Haddrell, Allen E.2; Li, Zhi-Ming1; Reid, Jonathan P.2 | |
2017-11-27 | |
发表期刊 | JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES |
ISSN | 2169-897X |
EISSN | 2169-8996 |
出版年 | 2017 |
卷号 | 122期号:22 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; England |
英文摘要 | In order to quantify the kinetics of mass transfer between the gas and condensed phases in aerosol, physicochemical properties of the gas and condensed phases and kinetic parameters (mass/thermal accommodation coefficients) are crucial for estimating mass fluxes over a wide size range from the free molecule to continuum regimes. In this study, we report measurements of the evaporation kinetics of droplets of 1-butanol, ethylene glycol (EG), diethylene glycol (DEG), and glycerol under well-controlled conditions (gas flow rates and temperature) using the previously developed cylindrical electrode electrodynamic balance technique. Measurements are compared with a model that captures the heat and mass transfer occurring at the evaporating droplet surface. The aim of these measurements is to clarify the discrepancy in the reported values of mass accommodation coefficient ((M), equals to evaporation coefficient based on microscopic reversibility) for 1-butanol, EG, and DEG and improve the accuracy of the value of the diffusion coefficient for glycerol in gaseous nitrogen. The uncertainties in the thermophysical and experimental parameters are carefully assessed, the literature values of the vapor pressures of these components are evaluated, and the plausible ranges of the evaporation coefficients for 1-butanol, EG, and DEG as well as uncertainty in diffusion coefficient for glycerol are reported. Results show that (M) should be greater than 0.4, 0.2, and 0.4 for EG, DEG, and 1-butanol, respectively. The refined values are helpful for accurate prediction of the evaporation/condensation rates. |
英文关键词 | evaporation kinetics polyol droplets electrodynamic balance (EDB) evaporation coefficients diffusion constants |
领域 | 气候变化 |
收录类别 | SCI-E |
WOS记录号 | WOS:000418084500006 |
WOS关键词 | CONDENSATION NUCLEUS COUNTER ; MASS ACCOMMODATION COEFFICIENT ; GAS-PHASE DIFFUSION ; VAPOR-PRESSURE DATA ; PARTICLE COUNTERS ; ORGANIC-COMPOUNDS ; TRACE GASES ; WATER ; AEROSOL ; GROWTH |
WOS类目 | Meteorology & Atmospheric Sciences |
WOS研究方向 | Meteorology & Atmospheric Sciences |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/32717 |
专题 | 气候变化 |
作者单位 | 1.Northwest Inst Nucl Technol, Xian, Shaanxi, Peoples R China; 2.Univ Bristol, Sch Chem, Bristol, Avon, England |
推荐引用方式 GB/T 7714 | Su, Yong-Yang,Marsh, Aleksandra,Haddrell, Allen E.,et al. Evaporation Kinetics of Polyol Droplets: Determination of Evaporation Coefficients and Diffusion Constants[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,2017,122(22). |
APA | Su, Yong-Yang,Marsh, Aleksandra,Haddrell, Allen E.,Li, Zhi-Ming,&Reid, Jonathan P..(2017).Evaporation Kinetics of Polyol Droplets: Determination of Evaporation Coefficients and Diffusion Constants.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,122(22). |
MLA | Su, Yong-Yang,et al."Evaporation Kinetics of Polyol Droplets: Determination of Evaporation Coefficients and Diffusion Constants".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 122.22(2017). |
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