Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1002/2017JD026906 |
Snowmelt onset hinders bromine monoxide heterogeneous recycling in the Arctic | |
Burd, Justine A.1,2; Peterson, Peter K.1,2,3; Nghiem, Son V.4; Perovich, Don K.5; Simpson, William R.1,2 | |
2017-08-16 | |
发表期刊 | JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES |
ISSN | 2169-897X |
EISSN | 2169-8996 |
出版年 | 2017 |
卷号 | 122期号:15 |
文章类型 | Article |
语种 | 英语 |
国家 | USA |
英文摘要 | Reactive bromine radicals (bromine atoms, Br, and bromine monoxide, BrO) deplete ozone and alter tropospheric oxidation chemistry during the Arctic springtime (February-June). As spring transitions to summer (May-June) and snow begins to melt, reactive bromine events cease and BrO becomes low in summer. In this study, we explore the relationship between the end of the reactive bromine season and snowmelt timing. BrO was measured by Multi-AXis Differential Optical Absorption Spectrometer at Utqiagvik (Barrow), AK, from 2012 to 2016 and on drifting buoys deployed in Arctic sea ice from 2011 to 2016, a total of 13 site and year combinations. The BrO seasonal end date (SED) was objectively determined and was compared to surface-air-temperature-derived melt onset date (MOD). The SED was highly correlated with the MOD (N=13, R-2=0.983, RMS=1.9days), and BrO is only observed at subfreezing temperatures. In subsets of these sites and years where ancillary data were available, we observed that snowpack depth reduced and rain precipitation occurred within a few days of the SED. These data are consistent with snowpack melting hindering BrO recycling, which is necessary to maintain enhanced BrO concentrations. With a projected warmer Arctic, a shift to earlier snowmelt seasons could alter the timing and role of halogen chemical reactions in the Arctic with impacts on ozone depletion and mercury deposition. Plain Language Summary Reactive bromine events in the Arctic are common in spring and deplete ozone and cause mercury deposition. These events are affected by snow and ice, which are changing in the Arctic; therefore, we need to understand how environmental conditions affect reactive bromine chemistry. We find that the reactive bromine season ends when snowpack begins to melt. Through these full seasonal observations, we find that reactive bromine events occur to warmer temperatures than previously reported, with 0 degrees C being the observed threshold above which reactive bromine is absent. We also find that snow appears necessary for reactive bromine chemistry and rain stops this chemistry. Earlier snowmelt in a warmer Arctic would end the reactive bromine season earlier, decreasing late springtime ozone depletion and mercury deposition. |
英文关键词 | reactive halogens snow sea ice snowmelt bromine monoxide |
领域 | 气候变化 |
收录类别 | SCI-E |
WOS记录号 | WOS:000408349500035 |
WOS关键词 | OPTICAL-ABSORPTION SPECTROSCOPY ; SYNTHETIC-APERTURE-RADAR ; TROPOSPHERIC BRO COLUMNS ; LAYER OZONE DEPLETION ; BOUNDARY-LAYER ; SURFACE OZONE ; MAX-DOAS ; ICE ; AIR ; CHEMISTRY |
WOS类目 | Meteorology & Atmospheric Sciences |
WOS研究方向 | Meteorology & Atmospheric Sciences |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/32351 |
专题 | 气候变化 |
作者单位 | 1.Univ Alaska Fairbanks, Dept Chem & Biochem, Fairbanks, AK 99775 USA; 2.Univ Alaska Fairbanks, Inst Geophys, Fairbanks, AK 99775 USA; 3.Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA; 4.CALTECH, Jet Prop Lab, Pasadena, CA USA; 5.Cold Reg Res & Engn Lab, Hanover, NH USA |
推荐引用方式 GB/T 7714 | Burd, Justine A.,Peterson, Peter K.,Nghiem, Son V.,et al. Snowmelt onset hinders bromine monoxide heterogeneous recycling in the Arctic[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,2017,122(15). |
APA | Burd, Justine A.,Peterson, Peter K.,Nghiem, Son V.,Perovich, Don K.,&Simpson, William R..(2017).Snowmelt onset hinders bromine monoxide heterogeneous recycling in the Arctic.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,122(15). |
MLA | Burd, Justine A.,et al."Snowmelt onset hinders bromine monoxide heterogeneous recycling in the Arctic".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 122.15(2017). |
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