资源环境科技发展态势分析平台

Intense and frequent new particle formation (NPF) events have been observed in polluted urban environments, yet the dominant mechanisms are still under debate. To understand the key species and governing processes of NPF in polluted urban environments, we conducted comprehensive measurements in downtown Beijing during January – March 2018. We performed detailed analyses on sulfuric acid cluster composition and budget, as well as the chemical and physical properties of oxidized organic molecules. Our results demonstrate that the fast clustering of sulfuric acid (H₂SO₄) and base molecules triggered the NPF events, and oxidized organic molecules (OOMs) further helped grow the newly formed particles towards climate‐ and health‐relevant sizes. This synergistic role of H₂SO₄, base species, and OOMs in NPF is likely representative of polluted urban environments where abundant H₂SO₄ and base species usually co‐exist, and OOMs are with moderately low volatility when produced under high NO_x concentrations.