GSTDTAP  > 地球科学
DOI10.1073/pnas.2021117118
Cooperative formation of porous silica and peptides on the prebiotic Earth
Alexandra Navrotsky; Richard Hervig; James Lyons; Dong-Kyun Seo; Everett Shock; Albert Voskanyan
2021-01-12
发表期刊Proceedings of the National Academy of Science
出版年2021
英文摘要

Modern technology has perfected the synthesis of catalysts such as zeolites and mesoporous silicas using organic structure directing agents (SDA) and their industrial use to catalyze a large variety of organic reactions within their pores. We suggest that early in prebiotic evolution, synergistic interplay arose between organic species in aqueous solution and silica formed from rocks by dynamic dissolution–recrystallization. The natural organics, for example, amino acids, small peptides, and fatty acids, acted as SDA for assembly of functional porous silica structures that induced further polymerization of amino acids and peptides, as well as other organic reactions. Positive feedback between synthesis and catalysis in the silica–organic system may have accelerated the early stages of abiotic evolution by increasing the formation of polymerized species.

领域地球科学
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/310402
专题地球科学
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Alexandra Navrotsky,Richard Hervig,James Lyons,et al. Cooperative formation of porous silica and peptides on the prebiotic Earth[J]. Proceedings of the National Academy of Science,2021.
APA Alexandra Navrotsky,Richard Hervig,James Lyons,Dong-Kyun Seo,Everett Shock,&Albert Voskanyan.(2021).Cooperative formation of porous silica and peptides on the prebiotic Earth.Proceedings of the National Academy of Science.
MLA Alexandra Navrotsky,et al."Cooperative formation of porous silica and peptides on the prebiotic Earth".Proceedings of the National Academy of Science (2021).
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