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DOI10.1126/science.abc4284
Supertwisted spirals of layered materials enabled by growth on non-Euclidean surfaces
Yuzhou Zhao; Chenyu Zhang; Daniel D. Kohler; Jason M. Scheeler; John C. Wright; Paul M. Voyles; Song Jin
2020-10-23
发表期刊Science
出版年2020
英文摘要The growth of layered materials on flat substrates usually occurs in stacked layers, although defects or a lattice mismatch can induce strains that distort the shape of subsequent layers. However, these effects are usually small and can be uncontrolled. Zhao et al. now demonstrate the possibility of synthesizing multilayers of two-dimensional materials with certain twists between the layers induced by the presence of screw dislocations in combination with curved substrate surfaces. Different twist angles are achieved by varying the amount of nonplanarity and the character (conical or hyperbolic) of the surface. Science , this issue p. [442][1] Euclidean geometry is the fundamental mathematical framework of classical crystallography. Traditionally, layered materials are grown on flat substrates; growing Euclidean crystals on non-Euclidean surfaces has rarely been studied. We present a general model describing the growth of layered materials with screw-dislocation spirals on non-Euclidean surfaces and show that it leads to continuously twisted multilayer superstructures. This model is experimentally demonstrated by growing supertwisted spirals of tungsten disulfide (WS2) and tungsten diselenide (WSe2) draped over nanoparticles near the centers of spirals. Microscopic structural analysis shows that the crystal lattice twist is consistent with the geometric twist of the layers, leading to moiré superlattices between the atomic layers. [1]: /lookup/doi/10.1126/science.abc4284
领域气候变化 ; 资源环境
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/300293
专题气候变化
资源环境科学
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Yuzhou Zhao,Chenyu Zhang,Daniel D. Kohler,et al. Supertwisted spirals of layered materials enabled by growth on non-Euclidean surfaces[J]. Science,2020.
APA Yuzhou Zhao.,Chenyu Zhang.,Daniel D. Kohler.,Jason M. Scheeler.,John C. Wright.,...&Song Jin.(2020).Supertwisted spirals of layered materials enabled by growth on non-Euclidean surfaces.Science.
MLA Yuzhou Zhao,et al."Supertwisted spirals of layered materials enabled by growth on non-Euclidean surfaces".Science (2020).
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