GSTDTAP  > 气候变化
DOI10.1002/2017GL076357
Oxidative Processing Lowers the Ice Nucleation Activity of Birch and Alder Pollen
Gute, Ellen; Abbatt, Jonathan P. D.
2018-02-16
发表期刊GEOPHYSICAL RESEARCH LETTERS
ISSN0094-8276
EISSN1944-8007
出版年2018
卷号45期号:3页码:1647-1653
文章类型Article
语种英语
国家Canada
英文摘要

Pollen carry water extractable compounds with ice nucleating (IN) activity. This study investigates whether the hydroxyl radical, as the major atmospheric oxidant, can affect the IN activity of silver birch and grey alder subpollen particles under in-cloud conditions for deposition freezing mode conditions at 234 K. It is found that oxidation increases the supersaturation ratio with respect to ice necessary for the onset of ice nucleation and decreases the fraction of particles which initiate ice nucleation. This reduction of IN activity under equivalent oxidation conditions does not occur with a mineral dust sample (Arizona Test Dust). Chemical analysis of fresh and oxidized pollen material indicates a change of molecular structure with a loss of conjugation and an increase in oxidized functional groups, such as carbonyls. This is the first demonstration that in-cloud oxidation may lower the IN abilities of biological particles such as pollen.


英文关键词ice nucleating particle pollen ice clouds oxidation in-cloud hydroxyl radical
领域气候变化
收录类别SCI-E
WOS记录号WOS:000426161800053
WOS关键词MINERAL DUST ; PARTICLES ; NUCLEI ; CONDENSATION ; PSEUDOMONAS ; CHEMISTRY ; IMMERSION ; RADICALS ; AEROSOLS ; CLIMATE
WOS类目Geosciences, Multidisciplinary
WOS研究方向Geology
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/28305
专题气候变化
作者单位Univ Toronto, Dept Chem, Toronto, ON, Canada
推荐引用方式
GB/T 7714
Gute, Ellen,Abbatt, Jonathan P. D.. Oxidative Processing Lowers the Ice Nucleation Activity of Birch and Alder Pollen[J]. GEOPHYSICAL RESEARCH LETTERS,2018,45(3):1647-1653.
APA Gute, Ellen,&Abbatt, Jonathan P. D..(2018).Oxidative Processing Lowers the Ice Nucleation Activity of Birch and Alder Pollen.GEOPHYSICAL RESEARCH LETTERS,45(3),1647-1653.
MLA Gute, Ellen,et al."Oxidative Processing Lowers the Ice Nucleation Activity of Birch and Alder Pollen".GEOPHYSICAL RESEARCH LETTERS 45.3(2018):1647-1653.
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