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DOI | 10.1073/pnas.1916673117 |
Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem" | |
Chang, Biao1,2; Li, Chao1; Liu, Deng1; Foster, Ian3; Tripati, Aradhna3,4,5; Lloyd, Max K.6; Maradiaga, Ingrid4,5; Luo, Genming1; An, Zhihui7; She, Zhenbing1; Xie, Shucheng1; Tong, Jinnan1; Huang, Junhua2; Algeo, Thomas J.1,2,8; Lyons, Timothy W.9; Immenhauser, Adrian10 | |
2020-06-08 | |
发表期刊 | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA |
ISSN | 0027-8424 |
出版年 | 2020 |
卷号 | 117期号:25页码:14005-14014 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; France; USA; Germany |
英文摘要 | Paleozoic and Precambrian sedimentary successions frequently contain massive dolomicrite [CaMg(CO3)(2)] units despite kinetic inhibitions to nucleation and precipitation of dolomite at Earth surface temperatures (<60 degrees C). This paradoxical observation is known as the "dolomite problem." Accordingly, the genesis of these dolostones is usually attributed to burial-hydrothermal dolomitization of primary limestones (CaCO3) at temperatures of >100 degrees C, thus raising doubt about the validity of these deposits as archives of Earth surface environments. We present a high-resolution, >63-My-long clumped-isotope temperature (T-Delta 47) record of shallow-marine dolomicrites from two drillcores of the Ediacaran (635 to 541 Ma) Doushantuo Formation in South China. Our T-Delta 47 record indicates that a majority (87%) of these dolostones formed at temperatures of <100 degrees C. When considering the regional thermal history, modeling of the influence of solid-state reordering on our T-Delta 47 record further suggests that most of the studied dolostones formed at temperatures of <60 degrees C, providing direct evidence of a low-temperature origin of these dolostones. Furthermore, calculated delta O-18 values of diagenetic fluids, rare earth element plus yttrium compositions, and petrographic observations of these dolostones are consistent with an early diagenetic origin in a rock-buffered environment. We thus propose that a precursor precipitate from seawater was subsequently dolomitized during early diagenesis in a near-surface setting to produce the large volume of dolostones in the Doushantuo Formation. Our findings suggest that the preponderance of dolomite in Paleozoic and Precambrian deposits likely reflects oceanic conditions specific to those eras and that dolostones can be faithful recorders of environmental conditions in the early oceans. |
英文关键词 | Doushantuo Formation clumped isotope early diagenesis carbonate geochemistry early oceans |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000546763100028 |
WOS关键词 | RARE-EARTH-ELEMENTS ; CLUMPED ISOTOPE ; DOUSHANTUO FORMATION ; MICROBIAL MEDIATION ; ACID FRACTIONATION ; SOUTH CHINA ; CARBONATE ; EVOLUTION ; DELTA(47) ; ORIGIN |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/274421 |
专题 | 地球科学 |
作者单位 | 1.China Univ Geosci, State Key Lab Biogeol & Environm Geol, Wuhan 430074, Peoples R China; 2.China Univ Geosci, State Key Lab Geol Proce & Mineral Resources, Wuhan 430074, Peoples R China; 3.Inst Univ European Mer, UMR6538 Geosci Ocean, F-29280 Plouzane, France; 4.Univ Calif Los Angeles, Dept Earth Planetary & Space Sci, Los Angeles, CA 90095 USA; 5.Univ Calif Los Angeles, Inst Environm & Sustainabil, Dept Atmospher & Ocean Sci, Los Angeles, CA 90095 USA; 6.CALTECH, Div Geol & Planetary Sci, Pasadena, CA 91125 USA; 7.Wuhan Inst Geol & Mineral Resources, Hubei Key Lab Paleontol & Geol Environm Evolut, Wuhan 430205, Peoples R China; 8.Univ Cincinnati, Dept Geol, Cincinnati, OH 45221 USA; 9.Univ Calif Riverside, Dept Earth & Planetary Sci, Riverside, CA 92521 USA; 10.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44801 Bochum, Germany |
推荐引用方式 GB/T 7714 | Chang, Biao,Li, Chao,Liu, Deng,et al. Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem"[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,2020,117(25):14005-14014. |
APA | Chang, Biao.,Li, Chao.,Liu, Deng.,Foster, Ian.,Tripati, Aradhna.,...&Immenhauser, Adrian.(2020).Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,117(25),14005-14014. |
MLA | Chang, Biao,et al."Massive formation of early diagenetic dolomite in the Ediacaran ocean: Constraints on the "dolomite problem"".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 117.25(2020):14005-14014. |
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