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DOI | 10.1038/s41467-020-14817-9 |
Silica accelerates the selective hydrogenation of CO2 to methanol on cobalt catalysts | |
Lingxiang Wang; Erjia Guan; Yeqing Wang; Liang Wang; Zhongmiao Gong; Yi Cui; Xiangju Meng; Bruce C. Gates; Feng-Shou Xiao | |
2020-02-25 | |
发表期刊 | Nature |
出版年 | 2020 |
英文摘要 | The reaction pathways on supported catalysts can be tuned by optimizing the catalyst structures, which helps the development of efficient catalysts. Such design is particularly desired for CO2 hydrogenation, which is characterized by complex pathways and multiple products. Here,聽we report an investigation of supported cobalt, which is known for its聽hydrocarbon production and聽ability to turn into a selective catalyst for methanol synthesis in CO2 hydrogenation which exhibits good activity and stability. The crucial technique is to use the silica, acting as a support and ligand, to modify the cobalt species via Co鈥扥鈥扴iOn linkages, which favor the reactivity of spectroscopically identified *CH3O intermediates, that more readily聽undergo hydrogenation to methanol than the C鈥扥 dissociation associated with聽hydrocarbon聽formation. Cobalt catalysts in this class offer appealing opportunities for optimizing selectivity in CO2 hydrogenation and producing high-grade methanol. By identifying聽this function of silica, we聽provide support for rationally controlling these reaction pathways. |
领域 | 资源环境 |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/249776 |
专题 | 资源环境科学 |
推荐引用方式 GB/T 7714 | Lingxiang Wang,Erjia Guan,Yeqing Wang,et al. Silica accelerates the selective hydrogenation of CO2 to methanol on cobalt catalysts[J]. Nature,2020. |
APA | Lingxiang Wang.,Erjia Guan.,Yeqing Wang.,Liang Wang.,Zhongmiao Gong.,...&Feng-Shou Xiao.(2020).Silica accelerates the selective hydrogenation of CO2 to methanol on cobalt catalysts.Nature. |
MLA | Lingxiang Wang,et al."Silica accelerates the selective hydrogenation of CO2 to methanol on cobalt catalysts".Nature (2020). |
条目包含的文件 | 条目无相关文件。 |
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