Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.5194/acp-20-5457-2020 |
Contribution of nitrous acid to the atmospheric oxidation capacity in an industrial zone in the Yangtze River Delta region of China | |
Zheng, Jun1; Shi, Xiaowen1; Ma, Yan1,2; Ren, Xinrong3,4,5; Jabbour, Halim1; Diao, Yiwei1,6; Wang, Weiwei6; Ge, Yifeng1; Zhang, Yuchan1; Zhu, Wenhui1 | |
2020-05-11 | |
发表期刊 | ATMOSPHERIC CHEMISTRY AND PHYSICS |
ISSN | 1680-7316 |
EISSN | 1680-7324 |
出版年 | 2020 |
卷号 | 20期号:9页码:5457-5475 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; USA |
英文摘要 | A suite of instruments was deployed to simultaneously measure nitrous acid (HONO), nitrogen oxides (NOx = NO + NO2), carbon monoxide (CO), ozone (O-3), volatile organic compounds (VOCs - including formaldehyde, HCHO) and meteorological parameters near a typical industrial zone in Nanjing in the Yangtze River Delta (YRD) region of China from 1 to 31 December 2015. High levels of HONO were detected using a wet-chemistry-based method. HONO ranged from 0.03 to 7.04 ppbv with an average of 1.32 +/- 0.92 ppbv. Elevated daytime HONO was frequently observed with a minimum of several hundred parts per trillion by volume (pptv) on average, which cannot be explained by the homogeneous OH + NO reaction (POH+NO) and primary emissions (P-emission), especially during periods with high particulate matter (PM2.5) loadings. HONO chemistry and its impact on the atmospheric oxidation capacity in the study area were further investigated using a Master Chemical Mechanism (MCM) box model. The results show that the average hydroxyl radical (OH) production rate was dominated by the photolysis of HONO (7.13 x 10(6) molec. cm(-3) s(-1)), followed by the ozonolysis of alkenes (3.94 x 10(6) molec. cm(-3) s(-1)), the photolysis of 03 (2.46 x 10(6) molec. cm(-3) s(-1)) and the photolysis of HCHO (1.60 x 10(6) molec. cm(-3) s(-1)) during the campaign period, especially within plumes that originated from the industrial zone. Model simulations indicated that heterogeneous chemistry played an important role in HONO formation. The average nighttime NO2 to HONO conversion rate was determined to be similar to 0.8 % h(-1). A good correlation between nocturnal HONO/NO2 and the product of particle surface area density (S/ V) and relative humidity (RH), S/ V . RH, supports the heterogeneous NO2/H2O reaction mechanism. The other HONO source, designated as P-unknonwn, was about twice as high as POH+NO on average and displayed a diurnal profile with an evidently photo-enhanced feature, i.e., photosensitized reactions of NO2 may be an important daytime HONO source. Nevertheless, our results suggest that daytime HONO formation was mostly due to the light-induced conversion of NO2 on aerosol surfaces, whereas heterogeneous NO2 reactions on the ground surface dominated nocturnal HONO production. Our study indicated that an elevated PM2.5 level during haze events can promote the conversion of NO2 to HONO by providing more heterogeneous reaction sites, thereby increasing the atmospheric oxidation capacity, which may further promote the formation of secondary air pollutants. |
领域 | 地球科学 |
收录类别 | SCI-E |
WOS记录号 | WOS:000531893600001 |
WOS关键词 | HONO VERTICAL GRADIENTS ; URBAN ATMOSPHERE ; HUMIC-ACID ; HETEROGENEOUS PRODUCTION ; SEASONAL-VARIATION ; ORGANIC-COMPOUNDS ; RURAL SITE ; NO2 ; CHEMISTRY ; DAYTIME |
WOS类目 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
WOS研究方向 | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/249081 |
专题 | 地球科学 |
作者单位 | 1.Nanjing Univ Informat Sci & Technol, Collaborat Innovat Ctr Atmospher Environm & Equip, Nanjing 210044, Peoples R China; 2.Nanjing Univ Informat Sci & Technol, NUIST Reading Acad, Nanjing 210044, Peoples R China; 3.NOAA, Air Resources Lab, College Pk, MD 20742 USA; 4.Univ Maryland, Dept Atmospher & Ocean Sci, College Pk, MD 20742 USA; 5.Univ Maryland, Cooperat Inst Satellite Earth Syst Studies, College Pk, MD 20742 USA; 6.Nanjing Univ Informat Sci & Technol, Sch Atmospher Phys, China Meteorol Adm, Key Lab Aerosol Cloud Precipitat, Nanjing 210044, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Jun,Shi, Xiaowen,Ma, Yan,et al. Contribution of nitrous acid to the atmospheric oxidation capacity in an industrial zone in the Yangtze River Delta region of China[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2020,20(9):5457-5475. |
APA | Zheng, Jun.,Shi, Xiaowen.,Ma, Yan.,Ren, Xinrong.,Jabbour, Halim.,...&Zhu, Wenhui.(2020).Contribution of nitrous acid to the atmospheric oxidation capacity in an industrial zone in the Yangtze River Delta region of China.ATMOSPHERIC CHEMISTRY AND PHYSICS,20(9),5457-5475. |
MLA | Zheng, Jun,et al."Contribution of nitrous acid to the atmospheric oxidation capacity in an industrial zone in the Yangtze River Delta region of China".ATMOSPHERIC CHEMISTRY AND PHYSICS 20.9(2020):5457-5475. |
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