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DOI | 10.1126/science.aaz1293 |
Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes | |
Yang, Ji1; Liu, Jiawang1; Neumann, Helfried1; Franke, Robert2,3; Jackstell, Railf1; Beller, Matthias1 | |
2019-12-20 | |
发表期刊 | SCIENCE |
ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2019 |
卷号 | 366期号:6472页码:1514-+ |
文章类型 | Article |
语种 | 英语 |
国家 | Germany |
英文摘要 | The direct carbonylation of 1,3-butadiene offers the potential for a more cost-efficient and environmentally benign route to industrially important adipic acid derivatives. However, owing to the complex reaction network of regioisomeric carbonylation and isomerization pathways, a selective practical catalyst for this process has thus far proven elusive. Here, we report the design of a pyridyl-substituted bidentate phosphine ligand (HeMaRaphos) that, upon coordination to palladium, catalyzes adipate diester formation from 1,3-butadiene, carbon monoxide, and butanol with 97% selectivity and 100% atom-economy under industrially viable and scalable conditions (turnover number > 60,000). This catalyst system also affords access to a variety of other di- and triesters from 1,2- and 1,3-dienes. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000503861000055 |
WOS关键词 | 1ST SYNTHESIS ; HYDROFORMYLATION ; ALKENES ; METHOXYCARBONYLATION ; ALKOXYCARBONYLATION ; CONVERSION ; ALCOHOLS ; CO2 |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/226509 |
专题 | 环境与发展全球科技态势 |
作者单位 | 1.Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany; 2.Evon Performance Mat GmbH, Paul Baumann Str 1, D-45772 Marl, Germany; 3.Ruhr Univ Bochum, Theoret Chem, D-44780 Bochum, Germany |
推荐引用方式 GB/T 7714 | Yang, Ji,Liu, Jiawang,Neumann, Helfried,et al. Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes[J]. SCIENCE,2019,366(6472):1514-+. |
APA | Yang, Ji,Liu, Jiawang,Neumann, Helfried,Franke, Robert,Jackstell, Railf,&Beller, Matthias.(2019).Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes.SCIENCE,366(6472),1514-+. |
MLA | Yang, Ji,et al."Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes".SCIENCE 366.6472(2019):1514-+. |
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