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DOI | 10.1126/science.aax9385 |
Wafer-scale synthesis of monolayer two-dimensional porphyrin polymers for hybrid superlattices | |
Zhong, Yu1; Cheng, Baorui1; Park, Chibeom1,2; Ray, Ariana3; Brown, Sarah1,2; Mujid, Fauzia1; Lee, Jae-Ung4,5; Zhou, Hua6; Suh, Joonki1; Lee, Kan-Heng4,7; Mannix, Andrew J.2; Kang, Kibum1,2,8; Sibener, S. J.1,2; Muller, David A.7; Park, Jiwoong1,2,4 | |
2019-12-13 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2019 |
卷号 | 366期号:6471页码:1379-+ |
文章类型 | Article |
语种 | 英语 |
国家 | USA; South Korea |
英文摘要 | The large-scale synthesis of high-quality thin films with extensive tunability derived from molecular building blocks will advance the development of artificial solids with designed functionalities. We report the synthesis of two-dimensional (2D) porphyrin polymer films with wafer-scale homogeneity in the ultimate limit of monolayer thickness by growing films at a sharp pentane/water interface, which allows the fabrication of their hybrid superlattices. Laminar assembly polymerization of porphyrin monomers could form monolayers of metal-organic frameworks with Cu2+ linkers or covalent organic frameworks with terephthalaldehyde linkers. Both the lattice structures and optical properties of these 2D films were directly controlled by the molecular monomers and polymerization chemistries. The 2D polymers were used to fabricate arrays of hybrid superlattices with molybdenum disulfide that could be used in electrical capacitors. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000502802300060 |
WOS关键词 | ELECTRONIC-STRUCTURE ; CHEMISTRY ; POLYMERIZATION ; SHEETS |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/226449 |
专题 | 环境与发展全球科技态势 |
作者单位 | 1.Univ Chicago, Dept Chem, 5735 S Ellis Ave, Chicago, IL 60637 USA; 2.Univ Chicago, James Franck Inst, 5640 S Ellis Ave, Chicago, IL 60637 USA; 3.Cornell Univ, Dept Phys, Ithaca, NY 14853 USA; 4.Univ Chicago, Pritzker Sch Mol Engn, Chicago, IL 60637 USA; 5.Ajou Univ, Dept Phys, Suwon 16499, South Korea; 6.Argonne Natl Lab, Adv Photon Source, Lemont, IL 60439 USA; 7.Cornell Univ, Sch Appl & Engn Phys, Ithaca, NY 14853 USA; 8.Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Daejeon 34141, South Korea |
推荐引用方式 GB/T 7714 | Zhong, Yu,Cheng, Baorui,Park, Chibeom,et al. Wafer-scale synthesis of monolayer two-dimensional porphyrin polymers for hybrid superlattices[J]. SCIENCE,2019,366(6471):1379-+. |
APA | Zhong, Yu.,Cheng, Baorui.,Park, Chibeom.,Ray, Ariana.,Brown, Sarah.,...&Park, Jiwoong.(2019).Wafer-scale synthesis of monolayer two-dimensional porphyrin polymers for hybrid superlattices.SCIENCE,366(6471),1379-+. |
MLA | Zhong, Yu,et al."Wafer-scale synthesis of monolayer two-dimensional porphyrin polymers for hybrid superlattices".SCIENCE 366.6471(2019):1379-+. |
条目包含的文件 | 条目无相关文件。 |
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