GSTDTAP
DOI10.1029/2019JD030466
Direct Online Mass Spectrometry Measurements of Ice Nucleating Particles at a California Coastal Site
Cornwell, G. C.1,4; McCluskey, C. S.2,5; Levin, E. J. T.2; Suski, K. J.2,4; DeMott, P. J.2; Kreidenweis, S. M.2; Prather, K. A.1,3
2019-11-19
发表期刊JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
ISSN2169-897X
EISSN2169-8996
出版年2019
卷号124期号:22页码:12157-12172
文章类型Article
语种英语
国家USA
英文摘要

The formation of ice in clouds can strongly impact cloud properties and precipitation processes during storms, including atmospheric rivers. Sea spray aerosol (SSA) particles are relatively inefficient as ice nucleating particles (INPs) compared to mineral dust. However, due to the vast coverage of the Earth's surface by the oceans, a number of recent studies have focused on identifying sources of marine INPs, particularly in regions lacking a strong influence from dust. This study describes the integration, validation, and application of a system coupling a continuous flow diffusion chamber with a single particle mass spectrometer using a pumped counterflow virtual impactor to remove nonnucleated particles and selectively measure the composition of INPs with a detection efficiency of 3.10 x 10(-4). In situ measurements of immersion freezing INP composition were made at a coastal site in California using the integrated system. Mineral dust particles were the most abundant ice crystal residual type during the sampling period and found to be ice active despite having undergone atmospheric processing. SSA were more abundant in ambient measurements but represented only a minor fraction of the ice crystal residual population at -31 degrees C. Notably, the SSA particles that activated were enriched with organic nitrogen species that were likely transferred from the ocean. Calculations of ice nucleation active site densities were within good agreement with previous studies of mineral dust and SSA.


英文关键词ice-nucleating particles aerosol time-of-flight mass spectrometry dust
领域气候变化
收录类别SCI-E
WOS记录号WOS:000497053300001
WOS关键词SEA SPRAY AEROSOL ; MARINE BOUNDARY-LAYER ; MINERAL DUST ; MIXING STATE ; ATMOSPHERIC RIVERS ; NUCLEI ; PRECIPITATION ; IMMERSION ; FIELD ; PERFORMANCE
WOS类目Meteorology & Atmospheric Sciences
WOS研究方向Meteorology & Atmospheric Sciences
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/225791
专题环境与发展全球科技态势
作者单位1.Univ Calif San Diego, Dept Chem & Biochem, San Diego, CA 92103 USA;
2.Colorado State Univ, Dept Atmospher Sci, Ft Collins, CO 80523 USA;
3.Univ Calif San Diego, Scripps Inst Oceanog, San Diego, CA 92103 USA;
4.Pacific Northwest Natl Lab, Richland, WA 99352 USA;
5.Natl Ctr Atmospher Res, POB 3000, Boulder, CO 80307 USA
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GB/T 7714
Cornwell, G. C.,McCluskey, C. S.,Levin, E. J. T.,et al. Direct Online Mass Spectrometry Measurements of Ice Nucleating Particles at a California Coastal Site[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,2019,124(22):12157-12172.
APA Cornwell, G. C..,McCluskey, C. S..,Levin, E. J. T..,Suski, K. J..,DeMott, P. J..,...&Prather, K. A..(2019).Direct Online Mass Spectrometry Measurements of Ice Nucleating Particles at a California Coastal Site.JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES,124(22),12157-12172.
MLA Cornwell, G. C.,et al."Direct Online Mass Spectrometry Measurements of Ice Nucleating Particles at a California Coastal Site".JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 124.22(2019):12157-12172.
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