GSTDTAP  > 地球科学
DOI10.5194/acp-18-9831-2018
A very limited role of tropospheric chlorine as a sink of the greenhouse gas methane
Gromov, Sergey1,3,4; Brenninkmeijer, Carl A. M.1; Joeckel, Patrick2
2018-07-12
发表期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
ISSN1680-7316
EISSN1680-7324
出版年2018
卷号18期号:13页码:9831-9843
文章类型Article
语种英语
国家Germany; Russia
英文摘要

Unexpectedly large seasonal phase differences between CH4 concentration and its C-13 / C-12 isotopic ratio and their inter-annual variations observed in southern hemispheric time series have been attributed to the Cl + CH4 reaction, in which (CH4)-C-13 is discriminated strongly compared to OH + CH4, and have provided the only (indirect) evidence of a hemispheric-scale presence of oxidative cycle-relevant quantities of tropospheric atomic Cl. Our analysis of concurrent New Zealand and Antarctic time series of CH4 and CO mixing and isotope ratios shows that a corresponding C-13 / C-12 variability is absent in CO. Using the AC-GCM EMAC model and isotopic mass balancing for comparing the periods of presumably high and low Cl, it is shown that variations in extra-tropical Southern Hemisphere Cl cannot have exceeded 0.9 x 10(3) atoms cm(-3). It is demonstrated that the C-13 / C-12 ratio of CO is a sensitive indicator for the isotopic composition of reacted CH4 and therefore for its sources. Despite ambiguities about the yield of CO from CH4 oxidation (with this yield being an important factor in the budget of CO) and uncertainties about the isotopic composition of sources of CO (in particular biomass burning), the contribution of Cl to the removal of CH4 in the troposphere is probably much lower than currently assumed.


领域地球科学
收录类别SCI-E
WOS记录号WOS:000438465500003
WOS关键词LOWER ANTARCTIC STRATOSPHERE ; LARGE (CO)-C-13 DEFICIT ; OZONE HOLE CHEMISTRY ; ATMOSPHERIC METHANE ; ISOTOPIC COMPOSITION ; MOLECULAR CHLORINE ; C-13/C-12 RATIOS ; CL ATOM ; CYCLE 2 ; CO
WOS类目Environmental Sciences ; Meteorology & Atmospheric Sciences
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/21698
专题地球科学
作者单位1.Max Planck Inst Chem, Atmospher Chem Dept, Mainz, Germany;
2.Deutsch Zentrum Luft & Raumfahrt DLR, Inst Phys Atmosphare, Oberpfaffenhofen, Wessling, Germany;
3.Inst Global Climate & Ecol Roshydromet, Moscow, Russia;
4.RAS IGCE, Moscow, Russia
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GB/T 7714
Gromov, Sergey,Brenninkmeijer, Carl A. M.,Joeckel, Patrick. A very limited role of tropospheric chlorine as a sink of the greenhouse gas methane[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2018,18(13):9831-9843.
APA Gromov, Sergey,Brenninkmeijer, Carl A. M.,&Joeckel, Patrick.(2018).A very limited role of tropospheric chlorine as a sink of the greenhouse gas methane.ATMOSPHERIC CHEMISTRY AND PHYSICS,18(13),9831-9843.
MLA Gromov, Sergey,et al."A very limited role of tropospheric chlorine as a sink of the greenhouse gas methane".ATMOSPHERIC CHEMISTRY AND PHYSICS 18.13(2018):9831-9843.
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