GSTDTAP  > 地球科学
DOI10.1073/pnas.1711472115
Impact of an historic underground gas well blowout on the current methane chemistry in a shallow groundwater system
Schout, Gilian1,2,3; Hartog, Niels2,3; Hassanizadeh, S. Majid2; Griffioen, Jasper1,4
2018-01-09
发表期刊PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
ISSN0027-8424
出版年2018
卷号115期号:2页码:296-301
文章类型Article
语种英语
国家Netherlands
英文摘要

Blowouts present a small but genuine risk when drilling into the deep subsurface and can have an immediate and significant impact on the surrounding environment. Nevertheless, studies that document their long-term impact are scarce. In 1965, a catastrophic underground blowout occurred during the drilling of a gas well in the Netherlands, which led to the uncontrolled release of large amounts of natural gas from the reservoir to the surface. In this study, the remaining impact on methane chemistry in the overlying aquifers was investigated. Methane concentrations higher than 10 mg/L (n = 12) were all found to have delta C-13-CH4 values larger than-30%, typical of a thermogenic origin. Both delta C-13-CH4 and delta D-CH4 correspond to the isotopic composition of the gas reservoir. Based on analysis of local groundwater flow conditions, this methane is not a remnant but most likely the result of ongoing leakage from the reservoir as a result of the blowout. Progressive enrichment of both delta C-13-CH4 and delta D-CH4 is observed with increasing distance and decreasing methane concentrations. The calculated isotopic fractionation factors of g(C) = 3 and g(D) = 54 suggest anaerobic methane oxidation is partly responsible for the observed decrease in concentrations. Elevated dissolved iron and manganese concentrations at the fringe of the methane plume show that oxidation is primarily mediated by the reduction of iron and manganese oxides. Combined, the data reveal the long-term impact that underground gas well blowouts may have on groundwater chemistry, as well as the important role of anaerobic oxidation in controlling the fate of dissolved methane.


英文关键词groundwater contamination well blowouts methane isotopic fingerprinting anaerobic methane oxidation
领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000419686400044
WOS关键词DRINKING-WATER WELLS ; LOS-ANGELES ; CONTAMINATION ; OXIDATION ; MARCELLUS ; CARBON ; OIL ; GEOCHEMISTRY ; HAZARDS
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
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被引频次:36[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/204912
专题地球科学
资源环境科学
气候变化
作者单位1.Univ Utrecht, Copernicus Inst Sustainable Dev, NL-3584 CS Utrecht, Netherlands;
2.Univ Utrecht, Earth Sci Dept, NL-3584 CD Utrecht, Netherlands;
3.KWR Water Cycle Res Inst, Geohydrol Unit, NL-3433 PE Nieuwegein, Netherlands;
4.Nederlandse Org Toegepast Nat Wetenschappelijk Ond, Geol Survey Netherlands, NL-3584 CB Utrecht, Netherlands
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GB/T 7714
Schout, Gilian,Hartog, Niels,Hassanizadeh, S. Majid,et al. Impact of an historic underground gas well blowout on the current methane chemistry in a shallow groundwater system[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,2018,115(2):296-301.
APA Schout, Gilian,Hartog, Niels,Hassanizadeh, S. Majid,&Griffioen, Jasper.(2018).Impact of an historic underground gas well blowout on the current methane chemistry in a shallow groundwater system.PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,115(2),296-301.
MLA Schout, Gilian,et al."Impact of an historic underground gas well blowout on the current methane chemistry in a shallow groundwater system".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 115.2(2018):296-301.
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