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DOI | 10.1073/pnas.1720619115 |
Natural diamond formation by self-redox of ferromagnesian carbonate | |
Chen, Ming1,2; Shu, Jinfu3; Xie, Xiande2,4; Tan, Dayong2,4; Mao, Ho-kwang3,5 | |
2018-03-13 | |
发表期刊 | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA |
ISSN | 0027-8424 |
出版年 | 2018 |
卷号 | 115期号:11页码:2676-2680 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; USA |
英文摘要 | Formation of natural diamonds requires the reduction of carbon to its bare elemental form, and pressures (P) greater than 5 GPa to cross the graphite-diamond transition boundary. In a study of shocked ferromagnesian carbonate at the Xiuyan impact crater, we found that the impact pressure-temperature (P-T) of 25-45 GPa and 800-900 degrees C were sufficient to decompose ankerite Ca(Fe2+, Mg)(CO3)(2) to form diamond in the absence of another reductant. The carbonate self-reduced to diamond by concurrent oxidation of Fe2+ to Fe3+ to form a high-P polymorph of magnesioferrite, MgFe23+O4. Discovery of the subsolidus carbonate self-reduction mechanism indicates that diamonds could be ubiquitously present as a dominant host for carbon in the Earth's lower mantle. |
英文关键词 | diamond self-redox ferromagnesium carbonate shock-metamorphism lower mantle |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000427245400051 |
WOS关键词 | HIGH-PRESSURE PHASE ; MINERAL INCLUSIONS ; XIUYAN CRATER ; EARTHS MANTLE ; SPECTROSCOPY ; SUBDUCTION ; INTERIOR ; COESITE ; MGFE2O4 ; CHINA |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/204877 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Isotope Geochem, Guangzhou 510640, Guangdong, Peoples R China; 2.Chinese Acad Sci, Guangzhou Inst Geochem, Key Lab Mineral & Metallogeny, Guangzhou 510640, Guangdong, Peoples R China; 3.Ctr High Pressure Sci & Technol Adv Res, Shanghai 201203, Peoples R China; 4.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Guangdong, Peoples R China; 5.Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA |
推荐引用方式 GB/T 7714 | Chen, Ming,Shu, Jinfu,Xie, Xiande,et al. Natural diamond formation by self-redox of ferromagnesian carbonate[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,2018,115(11):2676-2680. |
APA | Chen, Ming,Shu, Jinfu,Xie, Xiande,Tan, Dayong,&Mao, Ho-kwang.(2018).Natural diamond formation by self-redox of ferromagnesian carbonate.PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,115(11),2676-2680. |
MLA | Chen, Ming,et al."Natural diamond formation by self-redox of ferromagnesian carbonate".PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 115.11(2018):2676-2680. |
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