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DOI | 10.1038/s41467-019-10235-8 |
The fourth crystallographic closest packing unveiled in the gold nanocluster crystal | |
Gan, Zibao1; Chen, Jishi1; Wang, Juan2; Wang, Chengming3; Li, Man-Bo1; Yao, Chuanhao1; Zhuang, Shengli1; Xu, An2; Li, Lingling4; Wu, Zhikun1 | |
2019-06-03 | |
发表期刊 | NATURE COMMUNICATIONS |
ISSN | 2041-1723 |
出版年 | 2017 |
卷号 | 8 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China |
英文摘要 | Metal nanoclusters have recently attracted extensive interest not only for fundamental scientific research, but also for practical applications. For fundamental scientific research, it is of major importance to explore the internal structure and crystallographic arrangement. Herein, we synthesize a gold nanocluster whose composition is determined to be Au60S6( SCH2Ph)(36) by using electrospray ionization mass spectrometry and single crystal X- ray crystallography ( SCXC). SCXC also reveals that Au60S6( SCH2Ph)(36) consists of a fcc- like Au20 kernel protected by a pair of giant Au20S3( SCH2Ph) 18 staple motifs, which contain 6 tetrahedral- coordinate mu 4- S atoms not previously reported in the Au- S interface. Importantly, the fourth crystallographic closest- packed pattern, termed 6H left- handed helical ( 6HLH) arrangement, which results in the distinct loss of solid photoluminescence of amorphous Au60S6( SCH2Ph)(36), is found in the crystals of Au60S6( SCH2Ph)(36). The solventpolarity- dependent solution photoluminescence is also demonstrated. Overall, this work provides important insights about the structure, Au- S bonding and solid photoluminescence of gold nanoclusters. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000397291000001 |
WOS关键词 | ELECTROCATALYTIC PROPERTIES ; THEORETICAL-ANALYSIS ; NANOPARTICLES ; NANOCRYSTALS ; CLUSTERS ; PHASE ; SIZE ; NANOSTRUCTURES ; NANOMOLECULES ; TRANSITION |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/204393 |
专题 | 资源环境科学 |
作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, CAS Ctr Excellence Nanosci, Anhui Key Lab Nanomat & Nanotechnol,Key Lab Mat P, Hefei 230031, Peoples R China; 2.Chinese Acad Sci, Inst Tech Biol & Agr Engn, Key Lab Ion Beam Bioengn, Hefei 230031, Peoples R China; 3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China; 4.Shanghai Jiao Tong Univ, Instrumental Anal Ctr, Shanghai 200240, Peoples R China |
推荐引用方式 GB/T 7714 | Gan, Zibao,Chen, Jishi,Wang, Juan,et al. The fourth crystallographic closest packing unveiled in the gold nanocluster crystal[J]. NATURE COMMUNICATIONS,2019,8. |
APA | Gan, Zibao.,Chen, Jishi.,Wang, Juan.,Wang, Chengming.,Li, Man-Bo.,...&Wu, Zhikun.(2019).The fourth crystallographic closest packing unveiled in the gold nanocluster crystal.NATURE COMMUNICATIONS,8. |
MLA | Gan, Zibao,et al."The fourth crystallographic closest packing unveiled in the gold nanocluster crystal".NATURE COMMUNICATIONS 8(2019). |
条目包含的文件 | 条目无相关文件。 |
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