Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1038/s41467-019-08997-2 |
An isolable catenane consisting of two Mobius conjugated nanohoops | |
Fan, Yang-Yang1; Chen, Dandan2,3,4; Huang, Ze-Ao1; Zhu, Jun2,3,4; Tung, Chen-Ho1; Wu, Li-Zhu1; Cong, Huan1 | |
2019-03-06 | |
发表期刊 | NATURE COMMUNICATIONS |
ISSN | 2041-1723 |
出版年 | 2018 |
卷号 | 9 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China |
英文摘要 | Besides its mathematical importance, the Mobius topology (twisted, single-sided strip) is intriguing at the molecular level, as it features structural elegance and distinct properties; however, it carries synthetic challenges. Although some Mobius-type molecules have been isolated by synthetic chemists accompanied by extensive computational studies, the design, preparation, and characterization of stable Mobius-conjugated molecules remain a nontrivial task to date, let alone that of molecular Mobius strips assembling into more complex topologies. Here we report the efficient synthesis, crystal structure, and theoretical study of a catenane consisting of two fully conjugated nanohoops exhibiting Mobius topology in the solid state. This work highlights that oligoparaphenylene-derived nanohoops, a family of highly warped and synthetically challenging conjugated macrocycles, can not only serve as building blocks for interlocked supermolecular structures, but also represent a new class of compounds with isolable Mobius conformations stabilized by non-covalent interactions. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000440617500013 |
WOS关键词 | ELECTRON LOCALIZATION FUNCTION ; CRYSTAL-STRUCTURES ; DELOCALIZATION ; AROMATICITY ; MOLECULES ; HYDROCARBON ; CHEMISTRY |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/204248 |
专题 | 资源环境科学 |
作者单位 | 1.Univ Chinese Acad Sci, Chinese Acad Sci, Sch Future Technol, Tech Inst Phys & Chem,Key Lab Photochem Convers &, Beijing 100190, Peoples R China; 2.Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China; 3.Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat iChEM, Fujian Prov Key Lab Theoret & Computat Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China; 4.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China |
推荐引用方式 GB/T 7714 | Fan, Yang-Yang,Chen, Dandan,Huang, Ze-Ao,et al. An isolable catenane consisting of two Mobius conjugated nanohoops[J]. NATURE COMMUNICATIONS,2019,9. |
APA | Fan, Yang-Yang.,Chen, Dandan.,Huang, Ze-Ao.,Zhu, Jun.,Tung, Chen-Ho.,...&Cong, Huan.(2019).An isolable catenane consisting of two Mobius conjugated nanohoops.NATURE COMMUNICATIONS,9. |
MLA | Fan, Yang-Yang,et al."An isolable catenane consisting of two Mobius conjugated nanohoops".NATURE COMMUNICATIONS 9(2019). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论