Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1038/s41467-018-06995-4 |
A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity | |
Li, Xiao-Zhen1,2; Zhou, Li-Peng1; Yan, Liang-Liang1; Dong, Ya-Min3; Bai, Zhuan-Ling4,5; Sun, Xiao-Qi1,3; Juan Diwu4,5; Shuao Wang4,5; Bunzli, Jean-Claude6; Sun, Qing-Fu1 | |
2018-02-07 | |
发表期刊 | NATURE COMMUNICATIONS
![]() |
ISSN | 2041-1723 |
出版年 | 2018 |
卷号 | 9 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; Switzerland |
英文摘要 | Multivalent cooperativity plays an important role in the supramolecular self-assembly process. Herein, we report a remarkable cooperative enhancement of both structural integrity and metal ion selectivity on metal-organic M4L4 tetrahedral cages self-assembled from a tris-tridentate ligand (L-1) with a variety of metal ions spanning across the periodic table, including alkaline earth (Ca-II), transition (Cd-II), and all the lanthanide (Ln(III)) metal ions. All these M4L41 cages are stable to excess metal ions and ligands, which is in sharp contrast with the tridentate (L-2) ligand and bis-tridentate (L-3) ligand bearing the same coordination motif as L-1. Moreover, high-precision metal ion self-sorting is observed during the mixed-metal selfassembly of tetrahedral M4L4 cages, but not on the M2L3 counterparts. Based on the strong cooperative metal ion self-recognition behavior of M4L4 cages, a supramolecular approach to lanthanide separation is demonstrated, offering a new design principle of next-generation extractants for highly efficient lanthanide separation. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000424318100011 |
WOS关键词 | PHOTOPHYSICAL PROPERTIES ; SELF-RECOGNITION ; COMPLEXES ; BINDING ; DESIGN ; EXTRACTION ; LIGANDS ; CRYSTALLIZATION ; CONSTRUCTION ; ORGANIZATION |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/204062 |
专题 | 资源环境科学 |
作者单位 | 1.Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China; 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 3.Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen 361021, Peoples R China; 4.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China; 5.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China; 6.Swiss Fed Inst Technol, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland |
推荐引用方式 GB/T 7714 | Li, Xiao-Zhen,Zhou, Li-Peng,Yan, Liang-Liang,et al. A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity[J]. NATURE COMMUNICATIONS,2018,9. |
APA | Li, Xiao-Zhen.,Zhou, Li-Peng.,Yan, Liang-Liang.,Dong, Ya-Min.,Bai, Zhuan-Ling.,...&Sun, Qing-Fu.(2018).A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity.NATURE COMMUNICATIONS,9. |
MLA | Li, Xiao-Zhen,et al."A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity".NATURE COMMUNICATIONS 9(2018). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论