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DOI | 10.1038/s41467-018-04337-y |
Distinguishing faceted oxide nanocrystals with O-17 solid-state NMR spectroscopy | |
Li, Yuhong1,2,3; Wu, Xin-Ping4,5; Jiang, Ningxin1,2; Lin, Ming6; Shen, Li1,2; Sun, Haicheng1,2; Wang, Yongzheng1,2; Wang, Meng1,2; Ke, Xiaokang1,2; Yu, Zhiwu7; Gao, Fei8; Dong, Lin1,2,8; Guo, Xuefeng1,2; Hou, Wenhua1,2; Ding, Weiping1,2; Gong, Xue-Qing4,5; Grey, Clare P.9,10; Peng, Luming1,2 | |
2017-09-18 | |
发表期刊 | NATURE COMMUNICATIONS
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ISSN | 2041-1723 |
出版年 | 2017 |
卷号 | 8 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; Singapore; England; USA |
英文摘要 | Facet engineering of oxide nanocrystals represents a powerful method for generating diverse properties for practical and innovative applications. Therefore, it is crucial to determine the nature of the exposed facets of oxides in order to develop the facet/morphology-property relationships and rationally design nanostructures with desired properties. Despite the extensive applications of electron microscopy for visualizing the facet structure of nanocrystals, the volumes sampled by such techniques are very small and may not be representative of the whole sample. Here, we develop a convenient O-17 nuclear magnetic resonance (NMR) strategy to distinguish oxide nanocrystals exposing different facets. In combination with density functional theory calculations, we show that the oxygen ions on the exposed (001) and (101) facets of anatase titania nanocrystals have distinct O-17 NMR shifts, which are sensitive to surface reconstruction and the nature of the steps on the surface. The results presented here open up methods for characterizing faceted nanocrystalline oxides and related materials. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000411024900017 |
WOS关键词 | TIO2 NANOCRYSTALS ; TITANIUM-DIOXIDE ; ANATASE ; OXYGEN ; REACTIVITY ; NANOSHEETS ; SURFACE ; PERCENTAGE ; MORPHOLOGY ; CRYSTALS |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203812 |
专题 | 资源环境科学 |
作者单位 | 1.Nanjing Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Mesoscop Chem, Nanjing 210023, Jiangsu, Peoples R China; 2.Nanjing Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Chem Life Sci, Nanjing 210023, Jiangsu, Peoples R China; 3.Changshu Inst Technol, Sch Chem & Mat Engn, Jiangsu Lab Adv Funct Mat, Changshu 215500, Jiangsu, Peoples R China; 4.East China Univ Sci & Technol, Ctr Computat Chem, Key Lab Adv Mat, Shanghai 200237, Peoples R China; 5.East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China; 6.ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,08-03 Innovis, Singapore 138634, Singapore; 7.Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Anhui, Peoples R China; 8.Nanjing Univ, Ctr Modern Anal, Jiangsu Key Lab Vehicle Emiss Control, Nanjing 210093, Jiangsu, Peoples R China; 9.Univ Cambridge, Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England; 10.SUNY Stony Brook, Dept Chem, Stony Brook, NY 11974 USA |
推荐引用方式 GB/T 7714 | Li, Yuhong,Wu, Xin-Ping,Jiang, Ningxin,et al. Distinguishing faceted oxide nanocrystals with O-17 solid-state NMR spectroscopy[J]. NATURE COMMUNICATIONS,2017,8. |
APA | Li, Yuhong.,Wu, Xin-Ping.,Jiang, Ningxin.,Lin, Ming.,Shen, Li.,...&Peng, Luming.(2017).Distinguishing faceted oxide nanocrystals with O-17 solid-state NMR spectroscopy.NATURE COMMUNICATIONS,8. |
MLA | Li, Yuhong,et al."Distinguishing faceted oxide nanocrystals with O-17 solid-state NMR spectroscopy".NATURE COMMUNICATIONS 8(2017). |
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