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DOI | 10.1038/s41467-018-03739-2 |
Double dative bond between divalent carbon(O) and uranium | |
Su, Wei1; Pan, Sudip2; Sun, Xiong1; Wang, Shuao3,4; Zhao, Lili2; Frenking, Gernot2,5,6; Zhu, Congqing1 | |
2018-11-27 | |
发表期刊 | NATURE COMMUNICATIONS |
ISSN | 2041-1723 |
出版年 | 2018 |
卷号 | 9 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China; Germany; Spain |
英文摘要 | Dative bonds between p- and d-block atoms are common but species containing a double dative bond, which donate two-electron pairs to the same acceptor, are far less common. The synthesis of complexes between UCl4 and carbodiphosphoranes (CDP), which formally possess double dative bonds Cl4U paired left arrows CDP, is reported in this paper. Single-crystal X-ray diffraction shows that the uranium-carbon distances are in the range of bond lengths for uranium-carbon double bonds. A bonding analysis suggests that the molecules are uranium-carbone complexes featuring divalent carbon(O) ligands rather than uranium-carbene species. The complexes represent rare examples with a double dative bond in f-block chemistry. Our study not only introduces the concept of double dative bonds between carbones and f-block elements but also opens an avenue for the construction of other complexes with double dative bonds, thus providing new opportunities for the applications of f-block compounds. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000451310400002 |
WOS关键词 | MAIN-GROUP ; COORDINATION CHEMISTRY ; LIGAND PROPERTIES ; STABLE CARBENES ; U-IV=C ; COMPLEXES ; REACTIVITY ; VALENCE ; SINGLE ; CARBODICARBENE |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203758 |
专题 | 资源环境科学 |
作者单位 | 1.Nanjing Univ, State Key Lab Coordinat Chem, Jiangsu Key Lab Adv Organ Mat, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China; 2.Nanjing Tech Univ, Inst Adv Synth, Sch Chem & Mol Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Nanjing 211816, Jiangsu, Peoples R China; 3.Soochow Univ, State Key Lab Radiat Med & Protect, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China; 4.Soochow Univ, Collaborat Innovat Ctr Radiat Med, Jiangsu Higher Educ Inst, 199 Renai Rd, Suzhou 215123, Peoples R China; 5.Philipps Univ Marburg, Fachbereich Chemie, Hans Meerwein Str 4, D-35032 Marburg, Germany; 6.DIPC, PK 1072, Donostia San Sebastian 20080, Euskadi, Spain |
推荐引用方式 GB/T 7714 | Su, Wei,Pan, Sudip,Sun, Xiong,et al. Double dative bond between divalent carbon(O) and uranium[J]. NATURE COMMUNICATIONS,2018,9. |
APA | Su, Wei.,Pan, Sudip.,Sun, Xiong.,Wang, Shuao.,Zhao, Lili.,...&Zhu, Congqing.(2018).Double dative bond between divalent carbon(O) and uranium.NATURE COMMUNICATIONS,9. |
MLA | Su, Wei,et al."Double dative bond between divalent carbon(O) and uranium".NATURE COMMUNICATIONS 9(2018). |
条目包含的文件 | 条目无相关文件。 |
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