Global S&T Development Trend Analysis Platform of Resources and Environment
DOI | 10.1038/s41467-018-03693-z |
Selective reduction and homologation of carbon monoxide by organometallic iron complexes | |
Sharpe, Helen R.1,3; Geer, Ana M.1; Taylor, Laurence J.1; Gridley, Benjamin M.1,4; Blundell, Toby J.1; Blake, Alexander J.1; Davies, E. Stephen1; Lewis, William1; McMaster, Jonathan1; Robinson, David2; Kays, Deborah L.1 | |
2018-09-14 | |
发表期刊 | NATURE COMMUNICATIONS |
ISSN | 2041-1723 |
出版年 | 2018 |
卷号 | 9 |
文章类型 | Article |
语种 | 英语 |
国家 | England |
英文摘要 | Carbon monoxide is a key C-1 feedstock for the industrial production of hydrocarbons, where it is used to make millions of tonnes of chemicals, fuels, and solvents per annum. Many transition metal complexes can coordinate CO, but the formation of new C-C bonds in welldefined compounds from the scission and subsequent coupling of two or more CO moieties at a transition metal centre remains a challenge. Herein, we report the use of low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines and iron carboxylates at ambient temperature and pressure. A modification of the ligand framework allows for the isolation and structural characterisation of a proposed metallacyclic Fe(II) carbene intermediate. These results indicate that, with the appropriate choice of supporting ligands, it is possible to cleave and homologate carbon monoxide under mild conditions using an abundant and environmentally benign low-coordinate, first row transition metal. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000444554800014 |
WOS关键词 | RAY CRYSTAL-STRUCTURE ; SQUARAINE DYES ; CO HYDROGENATION ; URANIUM COMPLEX ; LIGANDS ; ACTIVATION ; INSERTION ; CLEAVAGE ; SINGLE ; DEOXYGENATION |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203737 |
专题 | 资源环境科学 |
作者单位 | 1.Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England; 2.Nottingham Trent Univ, Sch Sci & Technol, Dept Chem & Forens, Nottingham NG11 8NS, England; 3.Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England; 4.Kings Coll London, Dept Geog, Strand Bldg,Strand Campus, London WC2R 2LS, England |
推荐引用方式 GB/T 7714 | Sharpe, Helen R.,Geer, Ana M.,Taylor, Laurence J.,et al. Selective reduction and homologation of carbon monoxide by organometallic iron complexes[J]. NATURE COMMUNICATIONS,2018,9. |
APA | Sharpe, Helen R..,Geer, Ana M..,Taylor, Laurence J..,Gridley, Benjamin M..,Blundell, Toby J..,...&Kays, Deborah L..(2018).Selective reduction and homologation of carbon monoxide by organometallic iron complexes.NATURE COMMUNICATIONS,9. |
MLA | Sharpe, Helen R.,et al."Selective reduction and homologation of carbon monoxide by organometallic iron complexes".NATURE COMMUNICATIONS 9(2018). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论