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DOI | 10.1038/s41467-017-02692-w |
A [13]rotaxane assembled via a palladium molecular capsule | |
Ferrando-Soria, Jesus1,2,3; Fernandez, Antonio1,2,4; Asthana, Deepak1,2; Nawaz, Selina1,2; Vitorica-Yrezabal, Inigo J.1,2; Whitehead, George F. S.1,2; Muryn, Christopher A.1,2; Tuna, Floriana1,2; Timco, Grigore A.1,2; Burton, Neil D.1,2; Winpenny, Richard E. P.1,2 | |
2019-08-16 | |
发表期刊 | NATURE COMMUNICATIONS |
ISSN | 2041-1723 |
出版年 | 2019 |
卷号 | 10 |
文章类型 | Article |
语种 | 英语 |
国家 | England; Spain |
英文摘要 | Molecules that are the size of small proteins are difficult to make. The most frequently examined route is via self-assembly, and one particular approach involves molecular nanocapsules, where ligands are designed that will enforce the formation of specific polyhedra of metals within the core of the structure. Here we show that this approach can be combined with mechanically interlocking molecules to produce nanocapsules that are decorated on their exterior. This could be a general route to very large molecules, and is exemplified here by the synthesis and structural characterization of a [13]rotaxane, containing 150 metal centres. Small angle X-ray scattering combined with atomistic molecular dynamics simulations demonstrate the compound is intact in solution. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000481605000001 |
WOS关键词 | DYNAMICS ; SIMULATION ; COMPLEXES ; TEMPLATE ; NANOSCALE ; CHEMISTRY ; POLYHEDRA ; CATALYSIS ; POLYMERS ; STRATEGY |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203630 |
专题 | 资源环境科学 |
作者单位 | 1.Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England; 2.Univ Manchester, Photon Sci Inst, Oxford Rd, Manchester M13 9PL, Lancs, England; 3.Univ Valencia, ICMol, Dept Quim Inorgan, Valencia 46980, Paterna, Spain; 4.Loughborough Univ, Dept Chem, Sir David Davies Bldg, Loughborough LE11 3TU, Leics, England |
推荐引用方式 GB/T 7714 | Ferrando-Soria, Jesus,Fernandez, Antonio,Asthana, Deepak,et al. A [13]rotaxane assembled via a palladium molecular capsule[J]. NATURE COMMUNICATIONS,2019,10. |
APA | Ferrando-Soria, Jesus.,Fernandez, Antonio.,Asthana, Deepak.,Nawaz, Selina.,Vitorica-Yrezabal, Inigo J..,...&Winpenny, Richard E. P..(2019).A [13]rotaxane assembled via a palladium molecular capsule.NATURE COMMUNICATIONS,10. |
MLA | Ferrando-Soria, Jesus,et al."A [13]rotaxane assembled via a palladium molecular capsule".NATURE COMMUNICATIONS 10(2019). |
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