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DOI | 10.1038/ncomms15900 |
Flexible decapyrrylcorannulene hosts | |
Xu, Yun-Yan1; Tian, Han-Rui1; Li, Shu-Hui1; Chen, Zuo-Chang1; Yao, Yang-Rong1; Wang, Shan-Shan1; Zhang, Xin1; Zhu, Zheng-Zhong1; Deng, Shun-Liu1; Zhang, Qianyan1; Yang, Shangfeng2; Xie, Su-Yuan1; Huang, Rong-Bin1; Zheng, Lan-Sun1 | |
2019-01-30 | |
发表期刊 | NATURE COMMUNICATIONS |
ISSN | 2041-1723 |
出版年 | 2019 |
卷号 | 10 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China |
英文摘要 | The assembly of spherical fullerenes, or buckyballs, into single crystals for crystallographic identification often suffers from disordered arrangement. Here we show a chiral configuration of decapyrrylcorannulene that has a concave 'palm' of corannulene and ten flexible electronrich pyrryl group 'fingers' to mimic the smart molecular 'hands' for self-adaptably cradling various buckyballs in a (+) hand-ball-hand(-) mode. As exemplified by crystallographic identification of 15 buckyball structures representing pristine, exohedral, endohedral, dimeric and hetero-derivatization, the pyrryl groups twist with varying dihedral angles to adjust the interaction between decapyrrylcorannulene and fullerene. The self-adaptable electron-rich pyrryl groups, susceptible to methylation, are theoretically revealed to contribute more than the bowl-shaped palm of the corannulene in holding buckyball structures. The generality of the present decapyrrylcorannulene host with flexible pyrryl groups facilitates the visualization of numerous unknown/unsolved fullerenes by crystallography and the assembly of the otherwise close-packed spherical fullerenes into two-dimensional layered structures by intercalation. |
领域 | 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000457130800001 |
WOS关键词 | SUPRAMOLECULAR CHEMISTRY ; C-60 ; FULLERENE ; BOWL ; C-70 ; CORANNULENE ; HYDROCARBON ; DERIVATIVES |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/203386 |
专题 | 资源环境科学 |
作者单位 | 1.Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat, Dept Chem,State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China; 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, Dept Mat Sci & Engn,Synerget Innovat Ctr Quantum, Hefei 230026, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Yun-Yan,Tian, Han-Rui,Li, Shu-Hui,et al. Flexible decapyrrylcorannulene hosts[J]. NATURE COMMUNICATIONS,2019,10. |
APA | Xu, Yun-Yan.,Tian, Han-Rui.,Li, Shu-Hui.,Chen, Zuo-Chang.,Yao, Yang-Rong.,...&Zheng, Lan-Sun.(2019).Flexible decapyrrylcorannulene hosts.NATURE COMMUNICATIONS,10. |
MLA | Xu, Yun-Yan,et al."Flexible decapyrrylcorannulene hosts".NATURE COMMUNICATIONS 10(2019). |
条目包含的文件 | 条目无相关文件。 |
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