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DOI | 10.1126/science.aay1914 |
An sp-hybridized molecular carbon allotrope, cyclo[18]carbon | |
Kaiser, Katharina1; Scriven, Lorel M.2; Schulz, Fabian1; Gawel, Przemyslaw2; Gross, Leo1; Anderson, Harry L.2 | |
2019-09-20 | |
发表期刊 | SCIENCE |
ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2019 |
卷号 | 365期号:6459页码:1299-+ |
文章类型 | Article |
语种 | 英语 |
国家 | Switzerland; England |
英文摘要 | Carbon allotropes built from rings of two-coordinate atoms, known as cyclo[n] carbons, have fascinated chemists for many years, but until now they could not be isolated or structurally characterized because of their high reactivity. We generated cyclo[18] carbon (C-18) using atom manipulation on bilayer NaCl on Cu(111) at 5 kelvin by eliminating carbon monoxide from a cyclocarbon oxide molecule, C24O6. Characterization of cyclo[18] carbon by high-resolution atomic force microscopy revealed a polyynic structure with defined positions of alternating triple and single bonds. The high reactivity of cyclocarbon and cyclocarbon oxides allows covalent coupling between molecules to be induced by atom manipulation, opening an avenue for the synthesis of other carbon allotropes and carbon-rich materials from the coalescence of cyclocarbon molecules. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000487547400045 |
WOS关键词 | SCANNING TUNNELING MICROSCOPE ; CHEMICAL-STRUCTURE ; CRYSTAL-STRUCTURE ; ELECTRIC-FIELD ; CHARGE-STATE ; GENERATION ; RINGS ; C-60 ; NACL |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/202343 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.IBM Res Zurich, CH-8803 Ruschlikon, Switzerland; 2.Univ Oxford, Dept Chem, Oxford OX1 3TA, England |
推荐引用方式 GB/T 7714 | Kaiser, Katharina,Scriven, Lorel M.,Schulz, Fabian,et al. An sp-hybridized molecular carbon allotrope, cyclo[18]carbon[J]. SCIENCE,2019,365(6459):1299-+. |
APA | Kaiser, Katharina,Scriven, Lorel M.,Schulz, Fabian,Gawel, Przemyslaw,Gross, Leo,&Anderson, Harry L..(2019).An sp-hybridized molecular carbon allotrope, cyclo[18]carbon.SCIENCE,365(6459),1299-+. |
MLA | Kaiser, Katharina,et al."An sp-hybridized molecular carbon allotrope, cyclo[18]carbon".SCIENCE 365.6459(2019):1299-+. |
条目包含的文件 | 条目无相关文件。 |
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