Comment on "Activation of methane to CH3+: A selective industrial route to methanesulfonic acid"

doi:10.1126/science.aax7083

GSTDTAP > 地球科学

DOI	10.1126/science.aax7083
	Comment on "Activation of methane to CH3+: A selective industrial route to methanesulfonic acid"
	Roytman, Vladislav A.; Singleton, Daniel A.
	2019-05-10
发表期刊	SCIENCE
ISSN	0036-8075
EISSN	1095-9203
出版年	2019
卷号	364 期号:6440
文章类型	Editorial Material
语种	英语
国家	USA
英文摘要	Diaz-Urrutia and Ott (Reports, 22 March 2019, p. 1326) report a selective conversion of methane to methanesulfonic acid that is proposed to occur by a cationic chain reaction in which CH3+ adds to sulfur trioxide (SO3) to form CH3-S(O)(2)O+. This mechanism is not plausible because of the solvent reactivity of CH3+, the non-nucleophilicity of the sulfur atom of SO3, and the high energy of CH3-S(O)(2)O+.
领域	地球科学 ; 气候变化 ; 资源环境
收录类别	SCI-E ; SSCI
WOS记录号	WOS:000467631800001
WOS类目	Multidisciplinary Sciences
WOS研究方向	Science & Technology - Other Topics
引用统计
文献类型	期刊论文
条目标识符	http://119.78.100.173/C666/handle/2XK7JSWQ/201379
专题	地球科学资源环境科学气候变化
作者单位	Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
推荐引用方式 GB/T 7714	Roytman, Vladislav A.,Singleton, Daniel A.. Comment on "Activation of methane to CH3+: A selective industrial route to methanesulfonic acid"[J]. SCIENCE,2019,364(6440).
APA	Roytman, Vladislav A.,&Singleton, Daniel A..(2019).Comment on "Activation of methane to CH3+: A selective industrial route to methanesulfonic acid".SCIENCE,364(6440).
MLA	Roytman, Vladislav A.,et al."Comment on "Activation of methane to CH3+: A selective industrial route to methanesulfonic acid"".SCIENCE 364.6440(2019).