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DOI | 10.1126/science.aav9713 |
ORGANIC CHEMISTRY Copper's rapid ascent in visible-light photoredox catalysis | |
Hossain, Asik; Bhattacharyya, Aditya; Reiser, Oliver | |
2019-05-03 | |
发表期刊 | SCIENCE |
ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2019 |
卷号 | 364期号:6439页码:450-+ |
文章类型 | Review |
语种 | 英语 |
国家 | Germany |
英文摘要 | Visible-light photoredox catalysis offers a distinct activation mode complementary to thermal transition metal catalyzed reactions. The vast majority of photoredox processes capitalizes on precious metal ruthenium(II) or iridium(III) complexes that serve as single-electron reductants or oxidants in their photoexcited states. As a low-cost alternative, organic dyes are also frequently used but in general suffer from lower photostability. Copper-based photocatalysts are rapidly emerging, offering not only economic and ecological advantages but also otherwise inaccessible inner-sphere mechanisms, which have been successfully applied to challenging transformations. Moreover, the combination of conventional photocatalysts with copper(I) or copper(II) salts has emerged as an efficient dual catalytic system for cross-coupling reactions. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000466809600022 |
WOS关键词 | TRANSFER RADICAL-ADDITION ; CU-BASED SENSITIZERS ; MERGING PHOTOREDOX ; TERMINAL ALKYNES ; CROSS-COUPLINGS ; REGIOSELECTIVE SYNTHESIS ; COOPERATIVE PHOTOREDOX ; AEROBIC OXIDATION ; ELECTRON-TRANSFER ; METAL-COMPLEXES |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/201348 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | Univ Regensburg, Inst Organ Chem, Univ Str 31, D-93053 Regensburg, Germany |
推荐引用方式 GB/T 7714 | Hossain, Asik,Bhattacharyya, Aditya,Reiser, Oliver. ORGANIC CHEMISTRY Copper's rapid ascent in visible-light photoredox catalysis[J]. SCIENCE,2019,364(6439):450-+. |
APA | Hossain, Asik,Bhattacharyya, Aditya,&Reiser, Oliver.(2019).ORGANIC CHEMISTRY Copper's rapid ascent in visible-light photoredox catalysis.SCIENCE,364(6439),450-+. |
MLA | Hossain, Asik,et al."ORGANIC CHEMISTRY Copper's rapid ascent in visible-light photoredox catalysis".SCIENCE 364.6439(2019):450-+. |
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