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DOI | 10.1126/science.aap7883 |
Chiral Lewis acids integrated with single-walled carbon nanotubes for asymmetric catalysis in water | |
Kitanosono, Taku; Xu, Pengyu; Kobayashi, Shu | |
2018-10-19 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2018 |
卷号 | 362期号:6412页码:311-314 |
文章类型 | Article |
语种 | 英语 |
国家 | Japan |
英文摘要 | The development of highly reactive and stereoselective catalytic systems is required not only to improve existing synthetic methods but also to invent distinct chemical reactions. Herein, a homogenized combination of nickel-based Lewis acid-surfactant-combined catalysts and single-walled carbon nanotubes is shown to exhibit substantial activity in water. In addition to the enhanced reactivity, stereoselective performance and long-term stability were demonstrated in asymmetric conjugate addition reactions of aldoximes to furnish chiral nitrones in high yields with excellent selectivities. The practical and straightforward application of the designed catalysts in water provides an expedient, environmentally benign, and highly efficient pathway to access optically active compounds. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000447680100041 |
WOS关键词 | ENANTIOSELECTIVE SYNTHESIS ; CONJUGATE ADDITIONS ; DISPERSION ; ALDOXIMES ; LIGANDS |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/199880 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan |
推荐引用方式 GB/T 7714 | Kitanosono, Taku,Xu, Pengyu,Kobayashi, Shu. Chiral Lewis acids integrated with single-walled carbon nanotubes for asymmetric catalysis in water[J]. SCIENCE,2018,362(6412):311-314. |
APA | Kitanosono, Taku,Xu, Pengyu,&Kobayashi, Shu.(2018).Chiral Lewis acids integrated with single-walled carbon nanotubes for asymmetric catalysis in water.SCIENCE,362(6412),311-314. |
MLA | Kitanosono, Taku,et al."Chiral Lewis acids integrated with single-walled carbon nanotubes for asymmetric catalysis in water".SCIENCE 362.6412(2018):311-314. |
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