GSTDTAP  > 地球科学
DOI10.1126/science.aat0049
Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction
Yang, Jie1,2; Zhu, Xiaolei2,3; Wolf, Thomas J. A.2; Li, Zheng2,4,5; Nunes, J. Pedro F.6; Coffee, Ryan2,7,8; Cryan, James P.2; Guehr, Markus2,9; Hegazy, Kareem2,8; Heinz, Tony F.2,10; Jobe, Keith1; Li, Renkai1; Shen, Xiaozhe1; Veccione, Theodore1; Weathersby, Stephen1; Wilkin, Kyle J.11; Yoneda, Charles1; Zheng, Qiang1; Martinez, Todd J.2,3; Centurion, Martin11; Wang, Xijie1
2018-07-06
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2018
卷号361期号:6397页码:64-67
文章类型Article
语种英语
国家USA; Germany; England
英文摘要

Conical intersections play a critical role in excited-state dynamics of polyatomic molecules because they govern the reaction pathways of many nonadiabatic processes. However, ultrafast probes have lacked sufficient spatial resolution to image wave-packet trajectories through these intersections directly. Here, we present the simultaneous experimental characterization of one-photon and two-photon excitation channels in isolated CF3I molecules using ultrafast gas-phase electron diffraction. In the two-photon channel, we have mapped out the real-space trajectories of a coherent nuclear wave packet, which bifurcates onto two potential energy surfaces when passing through a conical intersection. In the one-photon channel, we have resolved excitation of both the umbrella and the breathing vibrational modes in the CF3 fragment in multiple nuclear dimensions. These findings benchmark and validate ab initio nonadiabatic dynamics calculations.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000437467100061
WOS关键词MOLECULAR-DYNAMICS ; SPECTROSCOPY ; PHOTOSYNTHESIS ; SPECTRA ; PULSES
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/199078
专题地球科学
资源环境科学
气候变化
作者单位1.SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA;
2.SLAC Natl Accelerator Lab, Stanford PULSE Inst, Menlo Pk, CA 94025 USA;
3.Stanford Univ, Dept Chem, Stanford, CA 94305 USA;
4.Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci, Hamburg, Germany;
5.Max Planck Inst Struct & Dynam Matter, Hamburg, Germany;
6.Univ York, Dept Chem, York, N Yorkshire, England;
7.SLAC Natl Accelerator Lab, Linac Coherent Light Source, Menlo Pk, CA USA;
8.Stanford Univ, Dept Phys, Stanford, CA 94305 USA;
9.Univ Potsdam, Inst Phys & Astron, Potsdam, Germany;
10.Stanford Univ, Dept Appl Phys, Stanford, CA 94305 USA;
11.Univ Nebraska, Dept Phys & Astron, Lincoln, NE 68588 USA
推荐引用方式
GB/T 7714
Yang, Jie,Zhu, Xiaolei,Wolf, Thomas J. A.,et al. Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction[J]. SCIENCE,2018,361(6397):64-67.
APA Yang, Jie.,Zhu, Xiaolei.,Wolf, Thomas J. A..,Li, Zheng.,Nunes, J. Pedro F..,...&Wang, Xijie.(2018).Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction.SCIENCE,361(6397),64-67.
MLA Yang, Jie,et al."Imaging CF3I conical intersection and photodissociation dynamics with ultrafast electron diffraction".SCIENCE 361.6397(2018):64-67.
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