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DOI | 10.1126/science.aai8625 |
Imaging the halogen bond in self-assembled halogenbenzenes on silver | |
Han, Zhumin1; Czap, Gregory1; Chiang, Chi-Lun1; Xu, Chen1; Wagner, Peter J.1; Wei, Xinyuan1,2,3,4; Zhang, Yanxing1,5; Wu, Ruqian1,2,3,4; Ho, W.1,6 | |
2017-10-13 | |
发表期刊 | SCIENCE |
ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2017 |
卷号 | 358期号:6360页码:206-+ |
文章类型 | Article |
语种 | 英语 |
国家 | USA; Peoples R China |
英文摘要 | Halogens are among the most electronegative elements, and the variations in size and polarizability of halogens require different descriptions of the intermolecular bonds they form. Here we use the inelastic tunneling probe (itProbe) to acquire real-space imaging of intermolecular-bonding structures in the two-dimensional self-assembly of halogenbenzene molecules on a metal surface. Direct visualization is obtained for the intermolecular attraction and the "windmill" pattern of bonding among the fully halogenated molecules. Our results provide a hitherto missing understanding of the nature of the halogen bond. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000412841500044 |
WOS关键词 | ATOMIC-FORCE MICROSCOPY ; SUPRAMOLECULAR CHEMISTRY ; MOLECULE |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/197105 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA; 2.Fudan Univ, State Key Lab Surface Phys, Shanghai 200433, Peoples R China; 3.Fudan Univ, Key Lab Computat Phys Sci MOE, Shanghai 200433, Peoples R China; 4.Fudan Univ, Dept Phys, Shanghai 200433, Peoples R China; 5.Henan Normal Univ, Coll Phys & Mat Sci, Xinxiang 453007, Henan, Peoples R China; 6.Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA |
推荐引用方式 GB/T 7714 | Han, Zhumin,Czap, Gregory,Chiang, Chi-Lun,et al. Imaging the halogen bond in self-assembled halogenbenzenes on silver[J]. SCIENCE,2017,358(6360):206-+. |
APA | Han, Zhumin.,Czap, Gregory.,Chiang, Chi-Lun.,Xu, Chen.,Wagner, Peter J..,...&Ho, W..(2017).Imaging the halogen bond in self-assembled halogenbenzenes on silver.SCIENCE,358(6360),206-+. |
MLA | Han, Zhumin,et al."Imaging the halogen bond in self-assembled halogenbenzenes on silver".SCIENCE 358.6360(2017):206-+. |
条目包含的文件 | 条目无相关文件。 |
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