Comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol"

doi:10.1126/science.aan5970

GSTDTAP > 地球科学

DOI	10.1126/science.aan5970
	Comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol"
	Periana, Roy A.
	2017-10-13
发表期刊	SCIENCE
ISSN	0036-8075
EISSN	1095-9203
出版年	2017
卷号	358 期号:6360
文章类型	Editorial Material
语种	英语
国家	USA
英文摘要	Sushkevich et al. (Reports, 5May 2017, p. 523) report on the use of water to oxidize methane to methanol. This seems problematic because the reaction of CH4 and water to generate methanol and H-2 is highly unfavorable at any temperature (Delta G of reaction approximate to +28 kcal/mol at 200 degrees C, equilibrium constant K approximate to 10(-13)). Consequently, even if the reaction is separated into two steps, it seems inconceivable to carry out such a net reaction in a practical manner.
领域	地球科学 ; 气候变化 ; 资源环境
收录类别	SCI-E
WOS记录号	WOS:000412841500001
WOS类目	Multidisciplinary Sciences
WOS研究方向	Science & Technology - Other Topics
URL	查看原文
引用统计
文献类型	期刊论文
条目标识符	http://119.78.100.173/C666/handle/2XK7JSWQ/197094
专题	地球科学资源环境科学气候变化
作者单位	Scripps Res Inst, Scripps Energy & Mat Ctr, Jupiter, FL 33458 USA
推荐引用方式 GB/T 7714	Periana, Roy A.. Comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol"[J]. SCIENCE,2017,358(6360).
APA	Periana, Roy A..(2017).Comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol".SCIENCE,358(6360).
MLA	Periana, Roy A.."Comment on "Selective anaerobic oxidation of methane enables direct synthesis of methanol"".SCIENCE 358.6360(2017).