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DOI | 10.1126/science.aao0453 |
Ruthenium-catalyzed insertion of adjacent diol carbon atoms into C-C bonds: Entry to type II polyketides | |
Bender, Matthias; Turnbull, Ben W. H.; Ambler, Brett R.; Krische, Michael J. | |
2017-08-25 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2017 |
卷号 | 357期号:6353页码:779-781 |
文章类型 | Article |
语种 | 英语 |
国家 | USA |
英文摘要 | Current catalytic processes involving carbon-carbon bond activation rely on p-unsaturated coupling partners. Exploiting the concept of transfer hydrogenative coupling, we report a ruthenium(0)-catalyzed cycloaddition of benzocyclobutenones that functionalizes two adjacent saturated diol carbon-hydrogen bonds. These regio- and diastereoselective processes enable convergent construction of type II polyketide substructures. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000408327900037 |
WOS关键词 | TRANSFER HYDROGENATION ; SINGLE BOND ; SUBSTITUTED PHENOLS ; OLEFIN INSERTION ; H BONDS ; ALKYNES ; ACTIVATION ; CLEAVAGE ; CYCLOBUTENONES ; CYCLOADDITION |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/196726 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | Univ Texas Austin, Dept Chem, Austin, TX 78712 USA |
推荐引用方式 GB/T 7714 | Bender, Matthias,Turnbull, Ben W. H.,Ambler, Brett R.,et al. Ruthenium-catalyzed insertion of adjacent diol carbon atoms into C-C bonds: Entry to type II polyketides[J]. SCIENCE,2017,357(6353):779-781. |
APA | Bender, Matthias,Turnbull, Ben W. H.,Ambler, Brett R.,&Krische, Michael J..(2017).Ruthenium-catalyzed insertion of adjacent diol carbon atoms into C-C bonds: Entry to type II polyketides.SCIENCE,357(6353),779-781. |
MLA | Bender, Matthias,et al."Ruthenium-catalyzed insertion of adjacent diol carbon atoms into C-C bonds: Entry to type II polyketides".SCIENCE 357.6353(2017):779-781. |
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