GSTDTAP  > 地球科学
DOI10.1126/science.aah6902
Direction-specific van der Waals attraction between rutile TiO2 nanocrystals
Zhang, Xin1; He, Yang2; Sushko, Maria L.1; Liu, Jia3; Luo, Langli3; De Yoreo, James J.1; Mao, Scott X.2; Wang, Chongmin3; Rosso, Kevin M.1
2017-04-28
发表期刊SCIENCE
ISSN0036-8075
EISSN1095-9203
出版年2017
卷号356期号:6336页码:433-+
文章类型Article
语种英语
国家USA
英文摘要

Mutual lattice orientations dictate the types and magnitudes of forces between crystalline particles. When lattice polarizability is anisotropic, the van der Waals dispersion attraction can, in principle, contribute to this direction dependence. We report measurement of this attraction between rutile nanocrystals, as a function of their mutual orientation and surface hydration extent. At tens of nanometers of separation, the attraction is weak and shows no dependence on azimuthal alignment or surface hydration. At separations of approximately one hydration layer, the attraction is strongly dependent on azimuthal alignment and systematically decreases as intervening water density increases. Measured forces closely agree with predictions from Lifshitz theory and show that dispersion forces can generate a torque between particles interacting in solution and between grains in materials.


领域地球科学 ; 气候变化 ; 资源环境
收录类别SCI-E
WOS记录号WOS:000400143000053
WOS关键词ORIENTED-ATTACHMENT ; CRYSTAL-GROWTH ; ENERGY ; FORCE ; WATER ; ANISOTROPY ; TRANSFORMATION ; ADSORPTION ; SURFACES ; ADHESION
WOS类目Multidisciplinary Sciences
WOS研究方向Science & Technology - Other Topics
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文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/195934
专题地球科学
资源环境科学
气候变化
作者单位1.Pacific Northwest Natl Lab, Phys & Computat Sci Directorate, Richland, WA 99352 USA;
2.Univ Pittsburgh, Dept Mech Engn & Mat Sci, Pittsburgh, PA 15260 USA;
3.Pacific Northwest Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA
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Zhang, Xin,He, Yang,Sushko, Maria L.,et al. Direction-specific van der Waals attraction between rutile TiO2 nanocrystals[J]. SCIENCE,2017,356(6336):433-+.
APA Zhang, Xin.,He, Yang.,Sushko, Maria L..,Liu, Jia.,Luo, Langli.,...&Rosso, Kevin M..(2017).Direction-specific van der Waals attraction between rutile TiO2 nanocrystals.SCIENCE,356(6336),433-+.
MLA Zhang, Xin,et al."Direction-specific van der Waals attraction between rutile TiO2 nanocrystals".SCIENCE 356.6336(2017):433-+.
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