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DOI | 10.1126/science.aal1585 |
The atom, the molecule, and the covalent organic framework | |
Diercks, Christian S.; Yaghi, Omar M.1 | |
2017-03-03 | |
发表期刊 | SCIENCE
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ISSN | 0036-8075 |
EISSN | 1095-9203 |
出版年 | 2017 |
卷号 | 355期号:6328 |
文章类型 | Review |
语种 | 英语 |
国家 | USA; Saudi Arabia |
英文摘要 | Just over a century ago, Lewis published his seminal work on what became known as the covalent bond, which has since occupied a central role in the theory of making organic molecules. With the advent of covalent organic frameworks (COFs), the chemistry of the covalent bond was extended to two-and three-dimensional frameworks. Here, organic molecules are linked by covalent bonds to yield crystalline, porous COFs from light elements (boron, carbon, nitrogen, oxygen, and silicon) that are characterized by high architectural and chemical robustness. This discovery paved the way for carrying out chemistry on frameworks without losing their porosity or crystallinity, and in turn achieving designed properties in materials. The recent union of the covalent and the mechanical bond in the COF provides the opportunity for making woven structures that incorporate flexibility and dynamics into frameworks. |
领域 | 地球科学 ; 气候变化 ; 资源环境 |
收录类别 | SCI-E |
WOS记录号 | WOS:000395181700031 |
WOS关键词 | RETICULAR CHEMISTRY ; DESIGNED SYNTHESIS ; CRYSTALLINE ; CONSTRUCTION ; FUNCTIONALIZATION ; TAXONOMY ; PORES ; NETS |
WOS类目 | Multidisciplinary Sciences |
WOS研究方向 | Science & Technology - Other Topics |
URL | 查看原文 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/195539 |
专题 | 地球科学 资源环境科学 气候变化 |
作者单位 | 1.Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA; 2.Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA; 3.Kavli Energy NanoSci Inst, Berkeley, CA 94720 USA; 4.Berkeley Global Sci Inst, Berkeley, CA 94720 USA; 5.King Abdulaziz City Sci & Technol, Riyadh 11442, Saudi Arabia |
推荐引用方式 GB/T 7714 | Diercks, Christian S.,Yaghi, Omar M.. The atom, the molecule, and the covalent organic framework[J]. SCIENCE,2017,355(6328). |
APA | Diercks, Christian S.,&Yaghi, Omar M..(2017).The atom, the molecule, and the covalent organic framework.SCIENCE,355(6328). |
MLA | Diercks, Christian S.,et al."The atom, the molecule, and the covalent organic framework".SCIENCE 355.6328(2017). |
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